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Merck
  • A new synthetic approach to 1,2,3,4-tetrahydroisoquinoline-3-carboxylic acid (Tic) derivatives via a [2 + 2 + 2] cycloaddition reaction.

A new synthetic approach to 1,2,3,4-tetrahydroisoquinoline-3-carboxylic acid (Tic) derivatives via a [2 + 2 + 2] cycloaddition reaction.

Bioorganic & medicinal chemistry letters (2000-07-11)
S Kotha, N Sreenivasachary
摘要

Tetrahydroisoquinoline-3-carboxylic acid derivatives are prepared via a [2 + 2 + 2] cycloaddition reaction as a key step using Wilkinson's and CpCo(CO)2 catalysts.

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Sigma-Aldrich
3-溴-1-(三甲基硅基)-1-丙炔, 98%