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Merck
  • Dodecaamide cages: organic 12-arm building blocks for supramolecular chemistry.

Dodecaamide cages: organic 12-arm building blocks for supramolecular chemistry.

Journal of the American Chemical Society (2013-06-22)
Jamie L Culshaw, Ge Cheng, Marc Schmidtmann, Tom Hasell, Ming Liu, Dave J Adams, Andrew I Cooper
摘要

A simple, one-step amidation reaction is used to produce a range of 12-arm organic building blocks for supramolecular chemistry via the derivatization of porous imine cages. As an example, microporous dendrimers are prepared.