- Lanthanum(III) triflate catalyzed direct amidation of esters.
Lanthanum(III) triflate catalyzed direct amidation of esters.
Organic letters (2014-03-26)
Hiroyuki Morimoto, Risa Fujiwara, Yuhei Shimizu, Kazuhiro Morisaki, Takashi Ohshima
PMID24660939
摘要
Lanthanum trifluoromethanesulfonate is an effective single-component catalyst for synthesizing a variety of amides directly from esters and amines under mild conditions. Highly selective amidation of esters and amines, as well as catalyst-controlled amidation of esters, demonstrated the effectiveness of the catalyst system.
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镧, foil, 25x25mm, thickness 0.125mm, as rolled, 99%
镧, rod, 100mm, diameter 6.35mm, cast, 99%
镧, rod, 50mm, diameter 6.35mm, cast, 99%
镧, foil, 100x100mm, thickness 0.1mm, as rolled, 99%
镧, foil, not light tested, 100x100mm, thickness 0.025mm, as rolled, 99%
镧, foil, 50x50mm, thickness 0.1mm, as rolled, 99%
镧, foil, 25x25mm, thickness 0.1mm, as rolled, 99%
镧, foil, not light tested, 25x25mm, thickness 0.025mm, as rolled, 99%
镧, foil, not light tested, 50x50mm, thickness 0.025mm, as rolled, 99%