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Merck
  • Metal-free direct oxidative intermolecular diarylation of anilides at ambient temperature assisted by cascade selective formation of C-C and C-N bonds.

Metal-free direct oxidative intermolecular diarylation of anilides at ambient temperature assisted by cascade selective formation of C-C and C-N bonds.

Chemical communications (Cambridge, England) (2012-02-15)
Rajarshi Samanta, Jonas Lategahn, Andrey P Antonchick
摘要

A new atom-economical process of direct oxidative intermolecular functionalization of aniline derivatives by simple arenes was developed. The products were formed in a highly regioselective manner under metal-free conditions at ambient temperature.

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Sigma-Aldrich
1-叔丁基-3,5-二甲基苯, 98%