跳转至内容
Merck
  • 1',3',3'-Trimethyl-2,3-diphenyl-2,3-di-hydro-isoxazole-5(4H)-spiro-2'-indoline.

1',3',3'-Trimethyl-2,3-diphenyl-2,3-di-hydro-isoxazole-5(4H)-spiro-2'-indoline.

Acta crystallographica. Section E, Structure reports online (2009-01-01)
Naoual Laghrib, Jean-Claude Daran, Rachid Fihi, Lhou Majidi, Mohamed Azrour
摘要

Two diastereoisomers of the title compound, C(25)H(26)N(2)O, have been prepared by cyclo-addition between 1,3,3-trimethyl-2-methyl-eneindoline and C-phenyl-N-phenyl-nitrone. The stereochemistry of the major diastereoisomer, viz. S,R/R,S, is confirmed by the X-ray analysis. The oxazole and the pyrole rings have envelope conformations. The packing is stabilized by weak C-H⋯π inter-actions involving the phenyl ring attached to the N atom of the oxazole and the phenyl ring of the indole fragment.

材料
货号
品牌
产品描述

Sigma-Aldrich
5-氯-1,3,3-三甲基-2-亚甲基吲哚啉, technical grade, 95%