- Total syntheses of (±)-securinine and (±)- allosecurinine.
Total syntheses of (±)-securinine and (±)- allosecurinine.
Organic letters (2012-08-24)
Jung-Hsuan Chen, Samantha R Levine, Jonas F Buergler, Travis C McMahon, Matthew R Medeiros, John L Wood
PMID22913575
摘要
Total syntheses of (±)-securinine and (±)-allosecurinine that employ a tandem rhodium carbenoid-initiated Claisen/α-ketol rearrangement sequence as a key step are described.