- Alcohol and water adsorption in zeolitic imidazolate frameworks.
Alcohol and water adsorption in zeolitic imidazolate frameworks.
Chemical communications (Cambridge, England) (2013-03-15)
Ke Zhang, Ryan P Lively, Michelle E Dose, Andrew J Brown, Chen Zhang, Jaeyub Chung, Sankar Nair, William J Koros, Ronald R Chance
PMID23486756
摘要
Alcohol (methanol, ethanol, 1-propanol, 2-propanol and 1-butanol) and water vapor adsorption in zeolitic imidazolate frameworks (ZIF-8, ZIF-71 and ZIF-90) with similar crystal sizes was systematically studied. The feasibility of applying these ZIF materials to the recovery of bio-alcohols is evaluated by estimating the vapor-phase alcohol-water sorption selectivity.