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Merck
  • Copper(I)-catalyzed cascade dearomatization of 2-substituted tryptophols with iodonium [corrected] salts.

Copper(I)-catalyzed cascade dearomatization of 2-substituted tryptophols with iodonium [corrected] salts.

Organic letters (2012-08-16)
Chuan Liu, Wei Zhang, Li-Xin Dai, Shu-Li You
摘要

Copper(I)-catalyzed dearomative arylation and vinylation of 2-substituted tryptophols were realized with a subsequent cyclization reaction. The cascade dearomatization sequence provided versatile furoindoline derivatives with two quaternary carbon centers in good to excellent yields.

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Sigma-Aldrich
3-(2-羟乙基)吲哚, 97%