An N-aryl-substituted oxazolidinone-containing ketone-catalyzed asymmetric epoxidation with hydrogen peroxide as the primary oxidant.

An N-aryl-substituted oxazolidinone-containing ketone-catalyzed asymmetric epoxidation with hydrogen peroxide as the primary oxidant.

The Journal of organic chemistry (2007-07-12)

Christopher P Burke, Lianhe Shu, Yian Shi

摘要

Asymmetric epoxidation of various olefins with an N-aryl-substituted oxazolidinone-containing ketone as catalyst and hydrogen peroxide as the primary oxidant has been investigated, and up to 96% ee was obtained.

材料

货号

品牌

产品描述

522864

Sigma-Aldrich

甲基苯乙烯, 60% meta, 40% para and 1% ortho, 99%, contains ~50 ppm 4-tert-butylcatechol as inhibitor