- Hydroaminations of unactivated alkenes with basic alkylamines: group 4 metal halide catalysts and Brønsted-acid organocatalysts.
Hydroaminations of unactivated alkenes with basic alkylamines: group 4 metal halide catalysts and Brønsted-acid organocatalysts.
Organic & biomolecular chemistry (2007-06-07)
Lutz Ackermann, Ludwig T Kaspar, Andreas Althammer
PMID17551648
摘要
Two distinct economical catalysts for intramolecular hydroaminations of electronically unactivated alkenes with basic amines are described, which are based on (a) group 4 metal halides under basic reaction conditions or (b) Brønsted-acid organocatalysts.
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