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Merck

CRM69056

Supelco

乙拌磷砜

certified reference material, TraceCERT®, Manufactured by: Sigma-Aldrich Production GmbH, Switzerland

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About This Item

经验公式(希尔记法):
C8H19O4PS3
CAS号:
分子量:
306.40
Beilstein:
1713538
MDL號碼:
分類程式碼代碼:
41116107
NACRES:
NA.24

等級

certified reference material
TraceCERT®

品質等級

產品線

TraceCERT®

形狀

liquid

儲存期限

limited shelf life, expiry date on the label

製造商/商標名

Manufactured by: Sigma-Aldrich Production GmbH, Switzerland

儲存溫度

2-8°C

SMILES 字串

CCOP(=S)(OCC)SCCS(=O)(=O)CC

InChI

1S/C8H19O4PS3/c1-4-11-13(14,12-5-2)15-7-8-16(9,10)6-3/h4-8H2,1-3H3

InChI 密鑰

BKVJOVPVLOJPKJ-UHFFFAOYSA-N

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相关类别

一般說明

This certified reference material (CRM) is produced and certified in accordance with ISO/IEC 17025 and ISO 17034. This CRM is traceable to primary material from an NMI, e.g. NIST or NMIJ.
Certified content by quantitative NMR incl. uncertainty and expiry date are given on the certificate.
Download your certificate at: http://www.sigma-aldrich.com
Disulfoton-sulfone is an oxidative metabolite of the organophosphorus insecticide disulfoton.
The European Union regulations define a maximum residue limit (MRL) of 0.01 mg/kg for disulfoton in foods of plant origin which is taken as a sum of disulfoton, disulfoton sulfoxide, and disulfoton sulfone. Currently, disulfoton is not allowed for its use in the European Union and also has restrictions over its use in the USA by American Environmental Protection Agency (EPA).

應用

The certified reference material (CRM) is intended to be used as a calibrant for chromatography and other analytical techniques.
The disulfoton-sulfone CRM may also find given below uses:
  • Determination of disulfoton and its five metabolites in human blood and urine samples by QuEChERS extraction followed by liquid chromatography-tandem mass spectrometric analysis
  • Method development for the analysis of 15 organophosphorus pesticides and their metabolites in water samples using multiwalled carbon nanotubes based dispersive solid phase extraction and gas chromatography-nitrogen phosphorus detector (GC-NPD)
  • Simultaneous determination of 15 organophosphorus pesticides and their metabolites in cereal-based baby food samples using multi-walled carbon nanotubes based dispersive solid phase extraction and gas chromatography-nitrogen phosphorus detector (GC-NPD)
  • Analysis of 11 pesticides and 4 of their metabolites in chickpeas and barley flours using a modified QuEChERS extraction and GC-NPD determination
  • Multi-residue determination of 60 pesticides in hen egg samples by liquid-chromatography and gas chromatography with tandem mass spectrometry, in combination with QuEChERS based sample pre-treatment
  • Method development to quantify 49 organophosphorus pesticide residues and 10 of their metabolites in fish, egg, and milk samples by means of dual gas chromatography-dual pulse flame photometric detection

推薦產品

Find a digital Reference Material for this product available on our online platform ChemisTwin® for NMR. You can use this digital equivalent on ChemisTwin® for your sample identity confirmation and compound quantification (with digital external standard). An NMR spectrum of this substance can be viewed and an online comparison against your sample can be performed with a few mouseclicks. Learn more here and start your free trial.

法律資訊

TraceCERT is a registered trademark of Merck KGaA, Darmstadt, Germany

象形圖

Skull and crossbones

訊號詞

Danger

危險聲明

危險分類

Acute Tox. 2 Oral

儲存類別代碼

6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials

水污染物質分類(WGK)

WGK 3

閃點(°F)

Not applicable

閃點(°C)

Not applicable


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分析证书(COA)

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Lixin Yang et al.
Journal of agricultural and food chemistry, 60(8), 1906-1913 (2012-02-04)
A new method for the quantitative determination of 49 kinds of organophosphorus pesticide residues and their metabolites in fish, egg, and milk by dual gas chromatography-dual pulse flame photometric detection was developed. Homogenized samples were extracted with acetone and methylene
Miguel Á González-Curbelo et al.
Journal of separation science, 35(2), 299-307 (2012-01-01)
Analytical potentiality of a modified version of the QuEChERS (Quick, Easy, Cheap, Effective, Rugged and Safe) method has been studied and validated for the extraction of a group of 11 pesticides (ethoprophos, cadusafos, dimethoate, terbufos, disulfoton, chlorpyrifos-methyl, fenitrothion, pirimiphos-methyl, malathion
Miguel Ángel González-Curbelo et al.
Journal of separation science, 36(3), 556-563 (2013-01-11)
In this manuscript, a dispersive SPE method based on the use of multiwalled carbon nanotubes has been developed for the determination of 15 organophosphorus pesticides residues including some of their metabolites (disulfoton sulfoxide, ethoprophos, cadusafos, dimethoate, terbufos, disulfoton, chlorpyrifos-methyl, malaoxon
Kiyotaka Usui et al.
Legal medicine (Tokyo, Japan), 14(6), 309-316 (2012-07-24)
A liquid chromatography-tandem mass spectrometry method was developed and validated for simultaneous determination of disulfoton and five of its oxidative metabolites (disulfoton-sulfoxide, disulfoton-sulfone, demeton-S, demeton-S-sulfoxide and demeton-S-sulfone) in human whole blood and urine. Extraction was undertaken using a QuEChERS method
Nho-Eul Song et al.
Food chemistry, 298, 125050-125050 (2019-07-02)
An analytical method involving QuEChERS (quick, easy, cheap, effective, rugged, and safe) sample preparation, followed by LC-MS/MS and GC-MS/MS was developed and validated for the determination of 60 pesticides in eggs. Recoveries of 70-120% were achieved for selected pesticides and

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