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反應適用性
reaction type: Photocatalysis
reagent type: catalyst
相关类别
一般說明
Penn PhD光反应器M2的特点和优点
- 模块化设计便于与365nm – 450nm的各种波长一起使用
- 360度反射环境可最大化表面积光子捕获
- 遮光罩互锁可防止用户暴露在有害光线下
- 交互式触摸屏可控制反应参数
- 已获得Intertek ETL、CE和CB认证
- 用户定义的参数，包括温度、光强度、风扇速度和搅拌速度
- 自动停止、暂停和重置选项
- 支持小瓶大小包括gc、4、8、20、40 ml
- 使用K型热电偶的温度反馈
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Photoredox catalysis is a powerful synthetic methodology to form challenging covalent bonds using light irradiation. It is effective for light-driven polymer and small molecule synthesis.
Effective Csp2- and Csp-hybridized coupling reactions established for catalysis, expanding to multi-step Csp3-coupling.
The application of radical chemistry towards organic synthesis is well-developed and wide-reaching, though often hampered by a dependence on toxic radical initiators.
自由基化学在有机合成中的应用已经过充分发展且影响广泛，但常常受制于对有毒自由基引发剂的依赖。
相关内容
Photoredox catalysis is a powerful synthetic methodology to form challenging covalent bonds using light irradiation. It is effective for light-driven polymer and small molecule synthesis.
Csp2- and Csp-hybridized coupling reactions are established catalytic approaches. However, multi-step Csp3- and Csp2-coupling reactions of boronic acids and related derivatives are still limited by ineffective two-electron transmetalation reactions.
While Markovnikov alkene reactivity is very well developed and utilized commonly in the synthesis of commodity and research chemicals, catalytic access to the anti-Markovnikov-selective adducts is a much less-developed endeavor.
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