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化驗
97%
形狀
liquid
折射率
n20/D 1.488
密度
1.107 g/mL at 25 °C
儲存溫度
2-8°C
SMILES 字串
O=C(OCCC=C)N1C=CN=C1
InChI
1S/C8H10N2O2/c1-2-3-6-12-8(11)10-5-4-9-7-10/h2,4-5,7H,1,3,6H2
InChI 密鑰
BNGLJMQCDKTXTL-UHFFFAOYSA-N
應用
1H-Imidazole-1-carboxylic acid-3-butenyl ester can be used:
- To prepare bis-naphthyridine derived cyclic mismatch binding ligands (CMBLs) which exhibit DNA repeat binding properties.
- As a reagent in the chemoselective esterification of carboxylic acids.
訊號詞
Warning
危險聲明
危險分類
Acute Tox. 4 Oral - Skin Sens. 1
儲存類別代碼
11 - Combustible Solids
水污染物質分類（WGK）
WGK 3
閃點（°F）
230.0 °F
閃點（°C）
110 °C
Design and synthesis of cyclic Mismatch-Binding Ligands (CMBLs) with variable linkers by Ring-Closing metathesis and their photophysical and DNA repeat binding properties
Mukherjee S, et al.
Chemistry?A European Journal , 23, 11385-11396 (2017)
Chemoselective esterification and amidation of carboxylic acids with imidazole carbamates and ureas
Heller ST and Sarpong R
Organic Letters, 12(20), 4572-4575 (2010)
相关内容
Professor Heller and coworkers are engaged in the development of mild and chemoselective acylation reactions using carbonylazole-derived reagents. To that end, they have developed a suite of carbonylimidazole derivatives for facile and chemoselective esterification (MImC, etc.) and amidation (WImC) of carboxylic acids, in collaboration with Professor Richmond Sarpong.
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