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Merck

749605

Sigma-Aldrich

2-(Diisopropylsilyl)pyridine

95%

别名:

PyDipSiH, Pyridyldiisopropylsilane

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About This Item

经验公式(希尔记法):
C11H19NSi
分子量:
193.36
MDL號碼:
分類程式碼代碼:
12352005
PubChem物質ID:

化驗

95%

折射率

n20/D 1.496

密度

0.917 g/mL at 25 °C

儲存溫度

2-8°C

SMILES 字串

CC(C)[SiH](C(C)C)c1ccccn1

InChI

1S/C11H19NSi/c1-9(2)13(10(3)4)11-7-5-6-8-12-11/h5-10,13H,1-4H3

InChI 密鑰

XPUAXJBYLPPFKA-UHFFFAOYSA-N

應用

Reagent commonly used in acyloxylation reactions

象形圖

Exclamation mark

訊號詞

Warning

危險聲明

危險分類

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

標靶器官

Respiratory system

儲存類別代碼

10 - Combustible liquids

水污染物質分類(WGK)

WGK 3

閃點(°F)

183.9 °F

閃點(°C)

84.4 °C


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Natalia Chernyak et al.
Journal of the American Chemical Society, 132(24), 8270-8272 (2010-06-01)
A new general and easily installable silicon-tethered pyridyl-containing directing group (PyDipSi) that allows for highly efficient and regioselective Pd-catalyzed ortho C-H acyloxylation of arenes has been developed. It has also been demonstrated that this directing group can efficiently be removed
The Pyridyldiisopropylsilyl Group: A Masked Functionality and Directing Group for Monoselective ortho-Acyloxylation and ortho-Halogenation Reactions of Arenes
Huang, C.; et al.
Advanced Synthesis & Catalysis, 353, 1285-1305 (2011)

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