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Sigma-Aldrich

Cerium(IV) oxide-samarium doped

nanopowder, contains 15 mol % samarium as dopant

Synonym(s):

SDC, Samarium-doped ceria

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About This Item

Empirical Formula (Hill Notation):
CeO2
Molecular Weight:
172.11
MDL number:
MFCD04974842
UNSPSC Code:
26111700
PubChem Substance ID:
24880634

form

nanopowder

contains

15 mol % samarium as dopant

composition

Ce0.85Sm0.15O2

reaction suitability

reagent type: catalyst
core: cerium

particle size

<100 nm

application(s)

battery manufacturing

SMILES string

[Sm].O=[Ce]=O

InChI

1S/Ce.2O.Sm

InChI key

AQGZISMLQKBRRO-UHFFFAOYSA-N

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General description

Cerium(IV) oxide-samarium doped nanopowder (15% mol samarium doped) (SDC) is an electrolytic material with a high oxygen ion conductivity. Samarium ion acts as an aliovalent cation that can be incorporated into the host lattice to increase the oxygen vacancy concentration and improve the oxide ion conduction in cerium oxide. It can be synthesized by reverse strike co-precipitation technique.
Samarium doped ceria may be used as an electrolyte in solid oxide fuel cells (SOFCs). Electrical conductivity as a function of temperature of doped ceria was investigated in a study. Relation of dopant type, oxygen vacancy ordering and ionic conductivity was investigated by transmission electron microscopy and electron energy loss spectroscopy.

Application

Cerium(IV) oxide-samarium doped can be used in the fabrication of solid oxide fuel cells (SOFCs), which can further be used as environmentally-friendly sources of alternative energy.

Packaging

Packaged in glass bottles

Storage Class Code

13 - Non Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

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Sigma-Aldrich

22390

Cerium(IV) oxide

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In this work, redox-active Mn or Cr is introduced to the B site of redox stable perovskite Sr(0.95)Ti(0.9)Nb(0.1)O3.00 to create oxygen vacancies in situ after reduction for high-temperature CO2 electrolysis. Combined analysis using X-ray diffraction, X-ray photoelectron spectroscopy, transmission electron
Diego H Sanchez et al.
PLoS genetics, 10(11), e1004806-e1004806 (2014-11-21)
Epigenetic mechanisms suppress the transcription of transposons and DNA repeats; however, this suppression can be transiently released under prolonged heat stress. Here we show that the Arabidopsis thaliana imprinted gene SDC, which is silent during vegetative growth due to DNA
Stephan Immenschuh et al.
Transplantation, 99(1), 56-62 (2014-08-15)
Treatment of patients with antibody-mediated rejection (AMR) after kidney transplantation by rituximab and plasmapheresis is ambiguous. Because of its unknown efficiency and serious side effects, biomarkers, which are predictive for responsiveness to this treatment in AMR patients, are required. Twenty
Fabrication and electrochemical properties of epitaxial samarium-doped ceria films on SrTiO3-buffered MgO substrates
Sanna S, et al.
Advances in Functional Materials, 19(11), 1713-1719 (2009)
AC impedance investigation of samarium-doped ceria."
Zhan Z, et al.
Journal of the Electrochemical Society, 148(5), A427-A432 (2001)
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