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Merck

IPr* an easily accessible highly hindered N-heterocyclic carbene.

Dalton transactions (Cambridge, England : 2003) (2010-01-28)
Guillaume Berthon-Gelloz, Maxime A Siegler, Anthony L Spek, Bernard Tinant, Joost N H Reek, István E Markó
PMID20104298
ABSTRACT

Herein, we wish to describe the efficient three-step synthesis of a novel highly hindered, but flexible, N-heterocyclic carbene and its coordination chemistry to Ag(i) and Rh(i).