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  • 2-Pyridinealdoxime, a new ligand for a Pd-precatalyst: application in solid-phase-assisted Suzuki-Miyaura reaction.

2-Pyridinealdoxime, a new ligand for a Pd-precatalyst: application in solid-phase-assisted Suzuki-Miyaura reaction.

Molecular diversity (2005-11-29)
Wladimir Solodenko, Christoph Brochwitz, Rudolf Wartchow, Md Abul Hashem, Kamal M Dawood, Michel Vaultier, Andreas Kirschning
PMID16311810
ABSTRACT

The preparation of a new palladium(II) complex with a 2-pyridinealdoxime ligand and its use as a Pd(0) precatalyst in the cross-coupling Suzuki-Miyaura reaction is described. Several concepts for the immobilization of this catalytic system are presented and compared in order to develop an efficient catalytic tool for high-throughput synthesis.