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About This Item
Linear Formula:
CF3C6H4CH2OH
CAS Number:
Molecular Weight:
176.14
Beilstein:
1450174
EC Number:
MDL number:
UNSPSC Code:
12352100
PubChem Substance ID:
Recommended Products
Assay
98%
refractive index
n20/D 1.459 (lit.)
bp
78-80 °C/4 mmHg (lit.)
density
1.286 g/mL at 25 °C (lit.)
SMILES string
OCc1ccc(cc1)C(F)(F)F
InChI
1S/C8H7F3O/c9-8(10,11)7-3-1-6(5-12)2-4-7/h1-4,12H,5H2
InChI key
MOOUWXDQAUXZRG-UHFFFAOYSA-N
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General description
Photocatalytic oxidation of 4-(trifluoromethyl)benzyl alcohol to corresponding aldehydes on TiO2 photocatalyst under O2 atmosphere has been reported.
Application
4-(Trifluoromethyl)benzyl alcohol was used:
- in the synthesis of highly electron-poor fluorine-containing alkenes
- as a reagent in kinetic studies of phosphonoformate prodrugs and aquachromium (IV)
Signal Word
Warning
Hazard Statements
Precautionary Statements
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
Target Organs
Respiratory system
Storage Class Code
10 - Combustible liquids
WGK
WGK 3
Flash Point(F)
213.8 °F - closed cup
Flash Point(C)
101 °C - closed cup
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves
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J. Chem. Soc. Perkin Trans. II, 1145-1145 (1992)
One-pot synthesis of fluorine-containing alkenes from in situ-generated stabilized phosphorus ylides.
Pakravan P, et al.
Phosphorus, Sulfur, and Silicon and the Related Elements, 182(3), 545-549 (2007)
Journal of the American Chemical Society, 114, 4205-4205 (1992)
Selective photocatalytic oxidation of benzyl alcohol and its derivatives into corresponding aldehydes by molecular oxygen on titanium dioxide under visible light irradiation.
Higashimoto S, et al.
J. Catal., 266(2), 279-285 (2009)
E Baciocchi et al.
European journal of biochemistry, 268(3), 665-672 (2001-02-13)
The H(2)O(2)-promoted oxidations of (R)-[alpha-(2)H(1)]-and (S)-[alpha-(2)H(1)]-arylalkanols catalysed by chloroperoxidase (CPO) from Caldariomyces fumago have been investigated. It has been found that with (R)-[alpha-(2)H(1)]-alcohols, the oxidation involves almost exclusively the cleavage of the C-H bond, whereas in the case of the
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