452823
(+)-Bis[(R)-1-phenylethyl]amine
99%
Synonym(s):
(+)-Bis[(R)-α-methylbenzyl]amine, [R-(R*,R*)]-(+)-Bis(α-methylbenzyl)amine
About This Item
Assay
99%
optical activity
[α]20/D +199.0°, neat
optical purity
ee: ≥99% (GLC)
refractive index
n20/D 1.5523 (lit.)
bp
86 °C/0.05 mmHg (lit.)
density
0.985 g/mL at 25 °C (lit.)
SMILES string
C[C@@H](N[C@H](C)c1ccccc1)c2ccccc2
InChI
1S/C16H19N/c1-13(15-9-5-3-6-10-15)17-14(2)16-11-7-4-8-12-16/h3-14,17H,1-2H3/t13-,14-/m1/s1
InChI key
NXLACVVNHYIYJN-ZIAGYGMSSA-N
Application
- In the synthesis of β-amino acids.
- In the preparation of chiral C(19)-C(26) and C(27)-C(32) moieties of scytophycin C.
- To induce enantioselectivity in the deprotonation of prochiral ketones.
- As a starting material for the synthesis of chiral phenolate ligands through Mannich condensation reaction.
- In the synthesis of chiral phosphoramidite ligands.
- To prepare chiral cyclic isoimidium salts, which are further used to synthesize chiral lactones through Diels-Alder reaction.
Signal Word
Warning
Hazard Statements
Precautionary Statements
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
Target Organs
Respiratory system
Storage Class Code
10 - Combustible liquids
WGK
WGK 3
Flash Point(F)
>235.4 °F - closed cup
Flash Point(C)
> 113 °C - closed cup
Personal Protective Equipment
Certificates of Analysis (COA)
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