- Rh(III)-catalyzed selective coupling of N-methoxy-1H-indole-1-carboxamides and aryl boronic acids.
Rh(III)-catalyzed selective coupling of N-methoxy-1H-indole-1-carboxamides and aryl boronic acids.
Organic letters (2014-06-25)
Jing Zheng, Yan Zhang, Sunliang Cui
PMID24959967
ABSTRACT
A Rh(III)-catalyzed selective coupling of N-methoxy-1H-indole-1-carboxamide and aryl boronic acids is reported. The coupling is mild and efficient toward diverse product formation, with selective C-C and C-C/C-N bond formation. Kinetic isotope effects studies were conducted to reveal a mechanism of C-H activation and electrophilic addition.
MATERIALS
Product Number
Brand
Product Description
Copper, tube, 1000mm, outside diameter 0.65mm, inside diameter 0.21mm, wall thickness 0.22mm, as drawn, 99.9%
Copper, tube, 1000mm, outside diameter 5.0mm, inside diameter 4mm, wall thickness 0.5mm, as drawn, 99.9%
Copper, sphere, 1000pcs, diameter 3.0mm, precision sphere grade 200
Copper, rod, 50mm, diameter 6.35mm, as drawn, 99.999%
Copper, tube, 100mm, outside diameter 1.75mm, inside diameter 0.33mm, wall thickness 0.71mm, as drawn, 99.9%
Copper, tube, 1000mm, outside diameter 12.7mm, inside diameter 10.26mm, wall thickness 1.22mm, as drawn, 99.9%
Copper, sphere, 100pcs, diameter 3.0mm, precision sphere grade 200
Copper, rod, 50mm, diameter 12.7mm, as drawn, 99.99+%
Copper, tube, 1000mm, outside diameter 6.0mm, inside diameter 4mm, wall thickness 1.0mm, as drawn, 99.9%
Copper - O.F.H.C., foil, 2m coil, thickness 0.7mm, half hard, 99.95+%
Copper, wire reel, 50m, diameter 0.25mm, as drawn, 99.99+%
Copper, wire reel, 1000m, diameter 0.04mm, hard, 99.9%
Copper, wire reel, 500m, diameter 0.125mm, annealed, 99.9%
Copper, wire reel, 2m, diameter 0.75mm, as drawn, 99.98+%
Copper, wire reel, 20m, diameter 0.5mm, as drawn, 99.999%
Copper, wire reel, 100m, diameter 0.5mm, as drawn, 99.98+%
Copper - O.F.H.C., foil, 6mm disks, thickness 0.125mm, hard, 99.95+%
Copper, wire reel, 500m, diameter 0.04mm, annealed, 99.9%
Copper, wire reel, 500m, diameter 0.15mm, annealed, silver plated, 99.9%
Copper, wire reel, 250m, diameter 0.04mm, annealed, 99.9%
Copper, wire reel, 50m, diameter 0.02mm, hard, 99.99+%
Copper, wire reel, 100m, diameter 0.5mm, annealed, silver plated, 99.9%
Copper - O.F.H.C., foil, 5m coil, thickness 0.125mm, hard, 99.95+%
Copper, wire reel, 1000m, diameter 0.075mm, annealed, 99.9%
Copper, wire reel, 100m, diameter 0.15mm, annealed, silver plated, 99.9%
Copper, wire reel, 0.2m, diameter 0.1mm, aluminum cladding, outside diameter 0.25mm, 99.9%
Copper, wire reel, 500m, diameter 0.1mm, annealed, 99.9%