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Merck

Mechanisms in manganese catalysed oxidation of alkenes with H2O2.

Chemical Society reviews (2012-12-15)
Pattama Saisaha, Johannes W de Boer, Wesley R Browne
ABSTRACT

The development of new catalytic systems for cis-dihydroxylation and epoxidation of alkenes, based on atom economic and environmentally friendly concepts, is a major contemporary challenge. In recent years, several systems based on manganese catalysts using H(2)O(2) as the terminal oxidant have been developed. In this review, selected homogeneous manganese catalytic systems, including 'ligand free' and pyridyl amine ligand based systems, that have been applied to alkene oxidation will be discussed with a strong focus on the mechanistic studies that have been carried out.

MATERIALS
Product Number
Brand
Product Description

Manganese, foil, not light tested, 50x50mm, thickness 0.0025mm, permanent polyester support, 98.7%
Manganese, foil, not light tested, 25x25mm, thickness 0.0025mm, permanent polyester support, 98.7%
Manganese, foil, not light tested, 50x50mm, thickness 0.01mm, permanent polyester support, 98.7%
Manganese, foil, not light tested, 25x25mm, thickness 0.006mm, permanent polyester support, 98.7%
Manganese, foil, not light tested, 25x25mm, thickness 0.01mm, permanent polyester support, 98.7%
Manganese, foil, not light tested, 50x50mm, thickness 0.015mm, permanent polyester support, 98.7%
Manganese, foil, not light tested, 50x50mm, thickness 0.003mm, permanent polyester support, 98.7%
Manganese, foil, not light tested, 25x25mm, thickness 0.007mm, permanent polyester support, 98.7%
Manganese, foil, not light tested, 50x50mm, thickness 0.004mm, permanent polyester support, 98.7%
Manganese, foil, not light tested, 25x25mm, thickness 0.008mm, permanent polyester support, 98.7%
Manganese, foil, 25x25mm, thickness 2mm, hot-pressed, 99.95%
Manganese, rod, 50mm, diameter 6.35mm, cast, 99.5%
Manganese, foil, not light tested, 50x50mm, thickness 0.0125mm, permanent polyester support, 98.7%
Manganese, foil, not light tested, 50x50mm, thickness 0.025mm, permanent polyester support, 98.7%
Manganese, foil, not light tested, 25x25mm, thickness 0.004mm, permanent polyester support, 98.7%
Manganese, foil, not light tested, 50x50mm, thickness 0.001mm, permanent polyester support, 98.7%
Manganese, foil, not light tested, 25x25mm, thickness 0.009mm, permanent polyester support, 98.7%
Manganese, foil, 50x50mm, thickness 2mm, hot-pressed, 99.95%
Manganese, foil, not light tested, 50x50mm, thickness 0.02mm, permanent polyester support, 98.7%
Manganese, foil, not light tested, 50x50mm, thickness 0.006mm, permanent polyester support, 98.7%
Manganese, foil, not light tested, 25x25mm, thickness 0.001mm, permanent polyester support, 98.7%
Manganese, rod, 10mm, diameter 4.0mm, cast, 99.5%
Manganese, foil, not light tested, 50x50mm, thickness 0.007mm, permanent polyester support, 98.7%
Manganese, foil, not light tested, 50x50mm, thickness 0.005mm, permanent polyester support, 98.7%
Manganese, foil, not light tested, 50x50mm, thickness 0.05mm, permanent polyester support, 98.7%
Manganese, foil, not light tested, 25x25mm, thickness 0.0125mm, permanent polyester support, 98.7%
Manganese, foil, not light tested, 50x50mm, thickness 0.008mm, permanent polyester support, 98.7%
Manganese, foil, not light tested, 25x25mm, thickness 0.003mm, permanent polyester support, 98.7%
Manganese, foil, not light tested, 25x25mm, thickness 0.05mm, permanent polyester support, 98.7%
Manganese, foil, not light tested, 25x25mm, thickness 0.002mm, permanent polyester support, 98.7%