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M1875

Sigma-Aldrich

Sodium malonate dibasic monohydrate

≥98% (non-aqueous titration)

Synonym(s):

Malonic acid disodium salt monohydrate, Propanedioic acid disodium salt monohydrate

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About This Item

Linear Formula:
CH2(CO2Na)2 · H2O
CAS Number:
26522-85-0
Molecular Weight:
166.04
Beilstein:
3772420
EC Number:
205-514-0
MDL number:
MFCD00002708
UNSPSC Code:
12352100
PubChem Substance ID:
57654361
NACRES:
NA.22

Assay

≥98% (non-aqueous titration)

SMILES string

O.[Na].OC(=O)CC(O)=O

InChI

1S/C3H4O4.2Na/c4-2(5)1-3(6)7;;/h1H2,(H,4,5)(H,6,7);;/q;2*+1/p-2

InChI key

PRWXGRGLHYDWPS-UHFFFAOYSA-L

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Application

Sodium malonate dibasic monohydrate can be used as a ligand to synthesize:
  • Bis(cyclopentadienyl)molybdenum malonate using molybdenocene dichloride in the presence of water.
  • Malonato complexes of manganese using manganese dichloride and 1,10-phenanthroline in the presence of methanol.
  • Metal-organic based polymeric complex using transition metal compound and urotropine.

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

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Idainés Feliciano et al.
Journal of biological inorganic chemistry : JBIC : a publication of the Society of Biological Inorganic Chemistry, 14(7), 1109-1117 (2009-06-19)
Two water-soluble molybdenocene complexes containing oxygen chelating ligands, maltolato and malonate, have been synthesized to elucidate the role of the ancillary ligands in the molybdenocene cytotoxic activity. The structural characterizations of these species by 1H NMR and IR spectroscopies suggest
Sanjit Konar et al.
Inorganic chemistry, 42(8), 2545-2552 (2003-04-15)
Two new metal-organic based polymeric complexes, [Cu(4)(O(2)CCH(2)CO(2))(4)(L)].7H(2)O (1) and [Co(2)(O(2)CCH(2)CO(2))(2)(L)].2H(2)O (2) [L = hexamethylenetetramine (urotropine)], have been synthesized and characterized by X-ray crystal structure determination and magnetic studies. Complex 1 is a 1D coordination polymer comprising a carboxylato bridged Cu(4)
Two new supramolecular malonato complexes of manganese (II): synthesis, crystal structure and magnetic property
Sain S, et al.
Inorganica chimica acta, 351, 12-20 (2003)
Milya Davlieva et al.
Nucleic acids research, 43(9), 4758-4773 (2015-04-22)
LiaR is a 'master regulator' of the cell envelope stress response in enterococci and many other Gram-positive organisms. Mutations to liaR can lead to antibiotic resistance to a variety of antibiotics including the cyclic lipopeptide daptomycin. LiaR is phosphorylated in
Alessio Innocenti et al.
Bioorganic & medicinal chemistry letters, 15(3), 573-578 (2005-01-25)
A detailed inhibition study of five carbonic anhydrase (CA, EC 4.2.1.1) isozymes with carboxylates including aliphatic (formate, acetate), dicarboxylic (oxalate, malonate), hydroxy/keto acids (l-lactate, l-malate, pyruvate), tricarboxylic (citrate), or aromatic (benzoate, tetrafluorobenzoate) representatives, some of which are important intermediates in
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