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Oligomers of cis-beta-norbornene amino acid: formation of beta-strand mimetics.

Chemical communications (Cambridge, England) (2006-04-01)
Srivari Chandrasekhar, Bathini Nagendra Babu, Anabathula Prabhakar, Ambadi Sudhakar, Marepally Srinivasa Reddy, Marelli Udaya Kiran, Bharatam Jagadeesh
RESUMEN

The oligomers of constrained cis-exo-beta-norbornene amino acid were synthesised and characterised by extensive NMR, CD, IR and MD studies. The results showed the formation of both right and left handed consecutive 6-membered hydrogen-bonded strands for [2S,3R] and [2R,3S] enantiomers, respectively.

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Sigma-Aldrich
Bicyclo[2.2.1]hept-2-ene, 99%