Skip to Content
Merck
All Photos(1)

Key Documents

View All Documentation

692220

Sigma-Aldrich

(R)-Ru(OAc)2(BINAP)

Synonym(s):

Diacetato[(R)-(+)-2,2′-bis(diphenylphosphino)-1,1′−binaphthyl]ruthenium(II)

Sign Into View Organizational & Contract Pricing
All Photos(1)

About This Item

Empirical Formula (Hill Notation):
C48H38O4P2Ru
CAS Number:
325146-81-4
Molecular Weight:
841.83
MDL number:
MFCD09753020
UNSPSC Code:
12352005
PubChem Substance ID:
329761476
NACRES:
NA.22

form

powder

storage temp.

2-8°C

SMILES string

CC(=O)O[Ru]OC(C)=O.c1ccc(cc1)P(c2ccccc2)c3ccc4ccccc4c3-c5c(ccc6ccccc56)P(c7ccccc7)c8ccccc8

InChI

1S/C44H32P2.2C2H4O2.Ru/c1-5-19-35(20-6-1)45(36-21-7-2-8-22-36)41-31-29-33-17-13-15-27-39(33)43(41)44-40-28-16-14-18-34(40)30-32-42(44)46(37-23-9-3-10-24-37)38-25-11-4-12-26-38;2*1-2(3)4;/h1-32H;2*1H3,(H,3,4);/q;;;+2/p-2

InChI key

NMLZYEWNUCRSRJ-UHFFFAOYSA-L

Application

Takasago Ligands and Complexes for Asymmetric Reactions
(R)-Ru(OAc)2(BINAP) may be used as a catalyst for the asymmetric hydrogenation of 1,1′-disubstituted olefins, such as 1-methyleneindan and 1-methylenetetralins. It can also catalyze the hydrogenation of 2-(trifluoromethyl)acrylic acid to form optically active 2-(trifluoromethyl)propionic acid.
Catalyst for:
  • Asymmetric hydrogenation reactions

Legal Information

Sold in collaboration with Takasago for research purposes only.

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

Already Own This Product?

Find documentation for the products that you have recently purchased in the Document Library.

Visit the Document Library

BINAP-Ru (II) and BINAP-Rh (I)-catalyzed asymmetric hydrogenation of olefins without heteroatom-functionalities
Ohta T, et al.
Journal of Organometallic Chemistry, 502(1-2), 169-176 (1995)
Preparation of optically active 2-(trifluoromethyl) alkan-1-ols by catalytic asymmetric hydrogenation.
Iseki K, et al.
Journal of Fluorine Chemistry, 69(1), 5-6 (1994)

Articles

Takasago Ligands

Hydrogenation, Asymmetric Catalysis, Binap, SEGPHOS®, Aldol reaction, Alkenylation, Arylation, Mannich reaction, Fluorination, Michael addition, Hydrosilylation, Cycloaddition, Takasago

Our team of scientists has experience in all areas of research including Life Science, Material Science, Chemical Synthesis, Chromatography, Analytical and many others.

Contact Technical Service