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Length-dependent extraction of single-walled carbon nanotubes.

Nano letters (2005-12-15)
Kirk J Ziegler, Daniel J Schmidt, Urs Rauwald, Kunal N Shah, Erica L Flor, Robert H Hauge, Richard E Smalley
ABSTRACT

A two-phase liquid-liquid extraction process is presented which is capable of extracting water-soluble single-walled carbon nanotubes into an organic phase. The extraction utilizes electrostatic interactions between a common phase transfer agent and the sidewall functional groups on the nanotubes. Large length-dependent van der Waals forces for nanotubes allow the ability to control the length of nanotubes extracted into the organic phase as demonstrated by atomic force microscopy.

MATERIALS
Product Number
Brand
Product Description

Sigma-Aldrich
Ammonium bromide, ≥99.99% trace metals basis
Sigma-Aldrich
Ammonium bromide, 99.999% trace metals basis
Sigma-Aldrich
Ammonium bromide, ACS reagent, ≥99.0%