53896

3-Phenylcyclobutanone

≥95.0% (HPLC)

• Empirical Formula (Hill Notation): C₁₀H₁₀O
• CAS Number: 52784-31-3
• Molecular Weight: 146.19
• UNSPSC Code: 12352100
• PubChem Substance ID: 329758016
• MDL number: MFCD04038993
• Assay: ≥95.0% (HPLC)
• Form: solid

Properties

• Quality Segment: 100
• assay: ≥95.0% (HPLC)
• form: solid
• refractive index: n20/D 1.544
• SMILES string: O=C1CC(C1)c2ccccc2
• InChI: 1S/C10H10O/c11-10-6-9(7-10)8-4-2-1-3-5-8/h1-5,9H,6-7H2
• InChI key: BVQSFCUGCAZOJQ-UHFFFAOYSA-N

Description

General description

Cationic Co(III)(salen) complex catalyzes the asymmetric Baeyer–Villiger reaction of 3-phenylcyclobutanone. Chiral N¹,N¹⁰-ethylene-bridged flavinium salts catalyzes the H₂O₂ oxidation of 3-phenylcyclobutanone to afford the corresponding lactones. 3-Phenylcyclobutanone can be synthesized from 2,2-dichloro3-phenylcyclobutenone.

Application

3-Phenylcyclobutanone may be used in synthesizing γ-butyrolactones and 2,4-bis(dimethylaminomethyl)-3-phenylcyclobutane.

Packaging

Bottomless glass bottle. Contents are inside inserted fused cone.

Safety Information

• Storage Class: 13 - Non Combustible Solids
• wgk: WGK 3
• flash_point_f: Not applicable
• flash_point_c: Not applicable
• ppe: Eyeshields, Gloves, type N95 (US)