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Vanadium(III) chloride

Name: Vanadium(III) chloride
Brand: MM
Price: 197 USD
Availability: InStock

99+

Synonym(s):

Vanadium(III) chloride, Vanadium trichloride

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Size/SKU	Availability	Price
25 g	Check Cart for Availability	$197.00

About This Item

Empirical Formula (Hill Notation):

Cl₃V

CAS Number:

7718-98-1

Molecular Weight:

157.30

UNSPSC Code:

12352302

EC Index Number:

231-744-6

NACRES:

NA.22

MDL number:

MFCD00011454

Form:

solid

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Properties

Quality Segment

200

form

solid

potency

350 mg/kg LD₅₀, oral (Rat)

greener alternative product characteristics

Catalysis
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density

3.0 g/cm³ at 20 °C

bulk density

1000 kg/m³

greener alternative category

Aligned

storage temp.

no temp limit

SMILES string

[V](Cl)(Cl)Cl

InChI

1S/3ClH.V/h3*1H;/q;;;+3/p-3

InChI key

HQYCOEXWFMFWLR-UHFFFAOYSA-K

Description

General description

We are committed to bringing you Greener Alternative Products, which adhere to one of the four categories of Greener Alternatives. This product falls under category 12 PAP and aligns with the Green Chemistry Principle of Catalysis. Click here for more information.

Application

Vanadium(III) chloride (VCl₃) can be used as a catalyst to synthesize:

Dihydropyrimidinone derivatives via a three-component Biginelli condensation reaction between aldehyde, β-keto ester, and urea (thiourea).
Coumarin derivatives via Pechmann condensation reaction of various phenols and β-keto esters.
β-amino alcohols by deprotection of epoxides with aromatic amines.
Diol derivatives by chemoselective cleavage of acetonides in methanol.

VCl₃ can also be used as a reducing agent to determine nitrates and nitrites in water samples.

Analysis Note

Assay (complexometric): ≥ 99.0 %
Identity (ICP-OES): passes test

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1 of 1

This Item	1.00824	200891	208272
Sigma-Aldrich 1.12393 Vanadium(III) chloride	Supelco 1.00824 Vanadium(V) oxide	Sigma-Aldrich 200891 Vanadium(V) oxychloride	Sigma-Aldrich 208272 Vanadium(III) chloride
form solid	form solid	form liquid	form powder
Quality Level 200	Quality Level 200	Quality Level 100	Quality Level 100
density 3.0 g/cm³ at 20 °C	density 3.36 g/cm³ at 20 °C	density 1.84 g/mL at 25 °C (lit.)	density 3 g/mL at 25 °C (lit.)
potency 350 mg/kg LD₅₀, oral (Rat)	potency 400-500 mg/kg LD₅₀, oral (Rat), >2000 mg/kg LD₅₀, skin (Rat)	potency -	potency -
bulk density 1000 kg/m³	bulk density 400‑600 kg/m³	bulk density -	bulk density -
storage temp. no temp limit	storage temp. 2-30°C	storage temp. -	storage temp. -

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pictograms

GHS05,GHS07

signalword

Danger

pcodes

P260 - P280 - P301 + P312 - P303 + P361 + P353 - P304 + P340 + P310 - P305 + P351 + P338

Hazard Classifications

Acute Tox. 4 Oral - Eye Dam. 1 - Skin Corr. 1B

supp_hazards

EUH014

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

hcodes

H302,H314

Storage Class

8B - Non-combustible corrosive hazardous materials

Certificates of Analysis (COA)

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