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Sigma-Aldrich

Boron trifluoride

≥99.5%

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About This Item

Empirical Formula (Hill Notation):
BF3
CAS Number:
7637-07-2
Molecular Weight:
67.81
EC Number:
231-569-5
MDL number:
MFCD00011316
UNSPSC Code:
12352106
PubChem Substance ID:
24857753
NACRES:
NA.22

vapor density

2.38 (21 °C, vs air)

assay

≥99.5%

form

gas

reaction suitability

core: boron
reagent type: Lewis acid
reagent type: catalyst
reaction type: Polymerization Reactions

bp

−100 °C (lit.)

mp

−127 °C (lit.)

SMILES string

FB(F)F

InChI

1S/BF3/c2-1(3)4

InChI key

WTEOIRVLGSZEPR-UHFFFAOYSA-N

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supp_hazards

EUH014

Storage Class

2A - Gases

wgk_germany

WGK 1

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Ramanathan Rajaganesh et al.
Carbohydrate research, 345(12), 1649-1657 (2010-06-29)
BF(3).Et(2)O-catalysed O-glycosylation of 1,2,3-tri-O-acetyl-4,6-O-butylidene- and ethylidene-beta-d-glucopyranose with different aliphatic and aromatic alcohols proceeds for the most part with complete retention of anomeric configuration. Antioxidant activity of O-glycosides shows significant inhibition (IC(50) approximately 77%). 1,3-Dipolar cycloaddition of terminal alkyne derivatives of
Joseph J Topczewski et al.
The Journal of organic chemistry, 74(18), 6965-6972 (2009-08-25)
The first total synthesis of (+)-schweinfurthin B, a potent and differentially active cytotoxic agent, has been accomplished. Completion of the synthesis required just 16 steps in the longest linear sequence from commercially available vanillin. Key synthetic transformations included a Shi
Ahmad Makahleh et al.
Talanta, 81(1-2), 20-24 (2010-03-02)
A reversed-phase high-performance liquid chromatographic method with capacitively coupled contactless conductivity detector (C(4)D) has been developed for the separation and the simultaneous determination of five underivatized long chain fatty acids (FAs), namely myristic, palmitic, stearic, oleic, and linoleic acids. An
G K Surya Prakash et al.
The Journal of organic chemistry, 74(22), 8659-8668 (2009-10-30)
BF(3)-monohydrate is found to be an efficient and strong acid catalyst as well as an effective protosolvating medium suitable for the hydroxyalkylation of arenes with aromatic aldehydes. This reaction has been extended to aromatic dialdehydes, such as terephthalic dicarboxaldehyde and
Masahiko Maekawa et al.
Dalton transactions (Cambridge, England : 2003), (3)(3), 415-417 (2009-01-06)
Three novel Cu(I)-C2H4 adducts bearing 4-(2-pyridyl)pyrimidine were self-assembled, and the roles of anion and solvent were proved in the formation process.
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