Skip to Content
Merck

[Chemical toxicological identification of esfenvalerate].

Sudebno-meditsinskaia ekspertiza (2012-08-11)
V K Shormanov, E N Chigareva, E N Vladimirenko
ABSTRACT

The optimal conditions for the isolation of esfenvalerate from the biological specimens have been determined. It was shown that this compound can be separated from the endogenous component of a biological material by means of liquid-liquid extraction and chromatography on a L 40/100 mcm silica gel column. The identification and quantitative analysis of esfenvalerate extracted from cadaveric liver and blood can be accomplished with the use of thin layer chromatography, UV and IR spectrophotometry as well as chromatomass spectrometry.

MATERIALS
Product Number
Brand
Product Description

Supelco
1,4-Dioxane solution, certified reference material, 2000 μg/mL in methanol, ampule of 1 mL
Sigma-Aldrich
1,4-Dioxane solution, NMR reference standard, 40% in benzene-d6 (99.6 atom % D), NMR tube size 10 mm × 8 in.
Supelco
1,4-Dioxane solution, NMR reference standard, 5 mM in benzene-d6 (99.6 atom % D), NMR tube size 3 mm × 8 in.
Supelco
1,4-Dioxane solution, NMR reference standard, 5 mM in chloroform-d (99.8 atom % D), NMR tube size 3 mm × 8 in.
Sigma-Aldrich
1,4-Dioxane solution, NMR reference standard, 10 mM in D2O ("100%", 99.96 atom % D), NMR tube size 5 mm × 7 in.
Supelco
1,4-Dioxane solution, NMR reference standard, 40% in benzene-d6 (99.6 atom % D), NMR tube size 5 mm × 8 in.
Supelco
1,4-Dioxane, analytical standard
Sigma-Aldrich
1,4-Dioxane solution, NMR reference standard, 40% in benzene-d6 (99.6 atom % D)
Sigma-Aldrich
1,4-Dioxane solution, NMR reference standard, 40% in benzene-d6 (99.6 atom % D), chromium(III) acetylacetonate 5 mg/mL, NMR tube size 3 mm × 8 in.
Sigma-Aldrich
1,4-Dioxane solution, NMR reference standard, 40% in benzene-d6 (99.6 atom % D), chromium(III) acetylacetonate 5 mg/mL, NMR tube size 5 mm × 8 in.
Sigma-Aldrich
1,4-Dioxane, ACS reagent, ≥99.0%, contains ≤25 ppm BHT as stabilizer
Sigma-Aldrich
1,4-Dioxane, puriss. p.a., ACS reagent, reag. ISO, reag. Ph. Eur., ≥99.5% (GC)
Sigma-Aldrich
1,4-Dioxane, ACS reagent, ≥99.0%
Sigma-Aldrich
1,4-Dioxane, suitable for HPLC, ≥99.5%
Sigma-Aldrich
Fenvalerate, ≥97%
Supelco
Esfenvalerate, PESTANAL®, analytical standard
Supelco
Fenvalerate, PESTANAL®, analytical standard