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  • One-pot synthesis of blue light-emitting Au nanoclusters and formation of photo-patternable composite films.

One-pot synthesis of blue light-emitting Au nanoclusters and formation of photo-patternable composite films.

Chemical communications (Cambridge, England) (2010-11-27)
Hiroshi Yabu
ABSTRACT

Blue light-emitting Au nanoclusters were synthesized in a simple one-pot process via reflux of Au ions with amino-terminated poly(1,2-butadiene) in toluene. DLS results and photoemission spectra showed that Au(8) nanoclusters were successfully formed. Moreover, photo-patterned films containing Au(8) clusters were prepared by photolithography.

MATERIALS
Product Number
Brand
Product Description

Sigma-Aldrich
Polybutadiene, cis, average Mw 200,000-300,000
Sigma-Aldrich
Polybutadiene, average Mn ~5,000
Sigma-Aldrich
Polybutadiene, predominantly 1,2-addition, approx. 90% 1,2-vinyl