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203645

Sigma-Aldrich

Lithium fluoride

greener alternative

powder, <100 μm, ≥99.98% trace metals basis

Synonym(s):

Fluorolithium

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About This Item

Linear Formula:
LiF
CAS Number:
7789-24-4
Molecular Weight:
25.94
EC Number:
232-152-0
MDL number:
MFCD00011090
UNSPSC Code:
12352302
PubChem Substance ID:
24852188
NACRES:
NA.23

Assay

≥99.98% trace metals basis

form

powder

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impurities

≤200.0 ppm Trace Metal Analysis

particle size

<100 μm

bp

1673 °C/1 atm (lit.)

mp

845 °C (lit.)

solubility

aqueous acid: slightly soluble(lit.)

density

2.64 g/mL at 25 °C (lit.)

greener alternative category

Enabling

SMILES string

[Li+].[F-]

InChI

1S/FH.Li/h1H;/q;+1/p-1

InChI key

PQXKHYXIUOZZFA-UHFFFAOYSA-M

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General description

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Application

Lithium fluoride can be used as an electron injection layer in the fabrication of electroluminescent devices.

It can be used as an electrolyte additive to protect the lithium metal electrode, which improves the stability and reversibility of the battery. The partially soluble LiF forms a thin coating over the surface of lithium and stabilizes the SEI layer.

It can also be used as catalyst support in the preparation of carbon nanofibers by a catalytic chemical vapor deposition method.

Features and Benefits

  • High mechanical strength
  • Wide electrochemical stability window
  • Low calculated barriers toLi diffusion

Pictograms

Exclamation mark
GHS07

Signal Word

Warning

Hazard Statements

H302,H319

Hazard Classifications

Acute Tox. 4 Oral - Eye Irrit. 2

Supplementary Hazards

EUH032

Storage Class Code

13 - Non Combustible Solids

WGK

WGK 2

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

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X W Meng et al.
The journal of physical chemistry. B, 115(16), 4768-4773 (2011-04-06)
On the basis of molecular dynamics simulations, we investigate water permeation across a single-walled carbon nanotube (SWCNT) under the influence of four symmetrical half-rings, each having six LiF dipolar molecules. The flux remains almost fixed as the separation, R, between
Christian Bernhardsson et al.
Health physics, 103(6), 740-749 (2012-11-01)
Laboratory studies have shown that ordinary household salt (NaCl) exhibits several promising properties for retrospective dosimetry; e.g., a linear dose response and a low detection limit, down to a few mGy or even less. In an attempt to test NaCl
Hatem Dachraoui et al.
Optics express, 19(3), 2797-2804 (2011-03-04)
We report a femtosecond crystallographic study of the dependence of the free-carries generation to the alignment of a crystalline sample to the laser polarization. The probe pulse transmission exhibits a π/2 modulation that is shown to be correlated with the
Asa Carlsson Tedgren et al.
Medical physics, 38(10), 5539-5550 (2011-10-14)
High energy photon beams are used in calibrating dosimeters for use in brachytherapy since absorbed dose to water can be determined accurately and with traceability to primary standards in such beams, using calibrated ion chambers and standard dosimetry protocols. For
Chilin Li et al.
Nano letters, 12(3), 1241-1246 (2012-02-07)
The thermodynamically required redistribution of ions at given interfaces is being paid increased attention. The present investigation of the contact LiF/TiO(2) offers a highly worthwhile example, as the redistribution processes can be predicted and verified. It consists in Li ion
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