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Merck

Half-sandwich arene ruthenium complexes: synthetic strategies and relevance in catalysis.

Chemical Society reviews (2013-11-07)
Prashant Kumar, Rakesh Kumar Gupta, Daya Shankar Pandey
ABSTRAKT

Half-sandwich arene ruthenium complexes exhibit versatile chemistry, serve as excellent precursors and find potential applications in many organic transformations. This review mainly focuses on the chemistry of piano-stool ruthenium complexes with special emphasis on the achiral or chiral-at-ruthenium center. Also, it deals with the synthesis, nomenclature and stereochemistry of arene ruthenium complexes along with mechanistic insights into the epimerization reactions and their applications in catalytic organic transformations with some selected examples.

MATERIAŁY
Numer produktu
Marka
Opis produktu

Sigma-Aldrich
Ruthenium black
Sigma-Aldrich
Ruthenium, powder, −200 mesh, 99.9% trace metals basis
Sigma-Aldrich
Ruthenium, powder
Ruthenium, Ruthenium, foil, 10x10mm, thickness 1.0mm, 99.9%
Ruthenium, Ruthenium, foil, 25x25mm, thickness 1.0mm, 99.9%
Ruthenium, Ruthenium, foil, 6x6mm, thickness 1.0mm, 99.9%
Ruthenium, Ruthenium, microfoil, disks, 10mm, thinness 0.025μm, specific density 30.5μg/cm2, permanent mylar 3.5μm support, 99.9%
Ruthenium, Ruthenium, bar, 50mm x 2mm x 2mm, 99.9%
Ruthenium, Ruthenium, microfoil, disks, 10mm, thinness 0.1μm, specific density 122μg/cm2, permanent mylar 3.5μm support, 99.9%
Ruthenium, Ruthenium, pellets, 2.5g, max. size 10mm, 99.9%
Ruthenium, Ruthenium, pellets, 5g, max. size 10mm, 99.9%
Ruthenium, Ruthenium, rod, 12.7mm, diameter 12.7mm, 99.9%
Ruthenium, Ruthenium, bar, 25mm x 2mm x 2mm, 99.9%