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Synthesis and crystal structure of hydroxyacetophenone Schiff bases containing propargyl moiety: solvent effects on UV-visible spectra.

Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy (2012-03-14)
V Selvarani, B Annaraj, M A Neelakantan, S Sundaramoorthy, D Velmurugan
ABSTRAKT

Four tetradentate (N(2)O(2)) and tridentate (NO(2)) Schiff base compounds (L1-L4) with propargyl moiety were prepared by the condensation of 1-[2-hydroxy-4-(prop-2-yn-1-yloxy)phenyl]ethanone with various aliphatic amines. The newly synthesized compounds (L1-L4) were characterized on the basis of the results of elemental analysis, thermal analysis, FT-IR, (1)H NMR spectroscopic studies and single crystal X-ray crystallography. The different bands observed in the electronic spectra of the compounds in various organic solvents have been assigned to the proper electronic transitions. The hydrogen bonding and tautomeric equilibria in both of solution and the solid state are explained. The solvatochromism of the synthesized compounds in different solvents in the UV-visible spectra are discussed.

MATERIAŁY
Numer produktu
Marka
Opis produktu

Supelco
Acetophenone, analytical standard
Sigma-Aldrich
Acetophenone, puriss. p.a., ≥99.0% (GC)
Sigma-Aldrich
Acetophenone, ≥98%, FG
Sigma-Aldrich
Acetophenone, ReagentPlus®, 99%