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89803

Methoxyamine hydrochloride

derivatization grade (GC derivatization), LiChropur, 97.5-102.5% (AT)

Synonim(y):

O-Methylhydroxylamine hydrochloride, Methoxylamine hydrochloride

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Gabaryty przesyłkiSKUDostępnośćCena netto
1 g
Skontaktuj się z Obsługą Klienta, aby uzyskać informacje na temat dostępności
215,00 zł
5 g
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739,00 zł

Informacje o tej pozycji

Wzór liniowy:
CH3ONH2 · HCl
Numer CAS:
Masa cząsteczkowa:
83.52
NACRES:
NA.05
UNSPSC Code:
41116105
Beilstein/REAXYS Number:
3589723
MDL number:
Assay:
97.5-102.5% (AT)
Form:
crystals

215,00 zł


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grade

derivatization grade (GC derivatization)

Quality Segment

assay

97.5-102.5% (AT)

form

crystals

quality

LiChropur

reaction suitability

reagent type: derivatization reagent
reaction type: Acylations

technique(s)

gas chromatography (GC): suitable

mp

151-154 °C (lit.)

SMILES string

Cl.CON

InChI

1S/CH5NO.ClH/c1-3-2;/h2H2,1H3;1H

InChI key

XNXVOSBNFZWHBV-UHFFFAOYSA-N

General description

Methoxyamine hydrochloride is a commonly used reagent for the generation of oxime derivatives of aldehyde- or ketone-group containing compounds. It is typically employed as an oximation reagent prior to silylation derivatizations.

Application

Methoxyamine hydrochloride can be used as:
  • A reagent for the preparation of O-methyl oximes.
  • A reagent used to make O-methyl oximes from aldehydes or ketones.
  • An alkylation reagent.
  • It may be used as a derivatization agent to improve the sensitivity of opioids,[1] steroids and ionic metabolites in biological samples and non-volatile flavor compounds in "Angeleno" plum fruit prior to the determination of analytes using gas chromatography-mass spectrometry (GC-MS) technique.

Other Notes

Discover LiChropur reagents ideal for HPLC or LC-MS analysis

Legal Information

LiChropur is a trademark of Merck KGaA, Darmstadt, Germany
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Ta pozycja
M652422690443504
assay

97.5-102.5% (AT)

assay

-

assay

98%

assay

99.0-101.0% (wt., AT)

reaction suitability

reagent type: derivatization reagent
reaction type: Acylations

reaction suitability

-

reaction suitability

-

reaction suitability

reagent type: derivatization reagent
reaction type: Alkylations

Quality Level

100

Quality Level

200

Quality Level

200

Quality Level

100

form

crystals

form

-

form

solid

form

-

mp

151-154 °C (lit.)

mp

-

mp

151-154 °C (lit.)

mp

130-133 °C (lit.)

grade

derivatization grade (GC derivatization)

grade

-

grade

-

grade

derivatization grade (GC derivatization)


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Explore all of our products under Methoxyamine hydrochloride


signalword

Danger

Hazard Classifications

Acute Tox. 4 Dermal - Acute Tox. 4 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Carc. 2 - Eye Irrit. 2 - Met. Corr. 1 - Skin Irrit. 2 - Skin Sens. 1 - STOT RE 1

Klasa składowania

6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable



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Dokumenty związane z niedawno zakupionymi produktami zostały zamieszczone w Bibliotece dokumentów.

Odwiedź Bibliotekę dokumentów



GC-MS analysis of multiply derivatized opioids in urine
Chen BG, et al.
Journal of Mass Spectrometry : Jms, 42(8), 1012-1023 (2007)
Solid-phase analytical derivatization for gas-chromatography-mass-spectrometry-based metabolomics
Takeo E, et al.
Journal of Bioscience and Bioengineering, 124(6), 700-706 (2017)
Microwave-assisted derivatization: application to steroid profiling by gas chromatography/mass spectrometry
Casals G, et al.
Journal of Chromatography. B, Biomedical Applications, 960(8), 8-13 (2014)



Numer pozycji handlu globalnego

SKUNUMER GTIN
89803-1G04061826642054
89803-5G04061833328347

Questions

1–3 of 3 Questions  
  1. How can I determine the shelf life / expiration / retest date of this product?

    1 answer
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/418/501/product-dating-information-06-25-mk.pdf

      Helpful?

  2. Once reconstituted (in pyridine), for how long can it be stored at -20 degrees?

    1 answer
    1. The solution stability of this product, when reconstituted in pyridine, has not been investigated. However, a previously available product, 225517, Methoxylamine hydrochloride solution 25-30 wt. % in H2O, offered a minimum shelf life of 1 year from the date of shipment, when stored at room temperature. Other online sources state that solutions prepared in DMSO are stable for 1 year when stored at -20°C and 2 years when stored at -80°C. Solutions prepared in high purity, dry pyridine may have exhibit similar stability.

      Helpful?

  3. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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