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87472

Hydrogen chloride solution

~3 M in 1-butanol, derivatization grade (GC derivatization), LiChropur

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Gabaryty przesyłkiSKUDostępnośćCena netto
50 mL
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301,00 zł
250 mL
Skontaktuj się z Obsługą Klienta, aby uzyskać informacje na temat dostępności
1020,00 zł

Informacje o tej pozycji

Numer CAS:
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352301
MDL number:
Beilstein/REAXYS Number:
1098214
Concentration:
~3 M in 1-butanol
Form:
solution
Grade:
derivatization grade (GC derivatization)

301,00 zł


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Nazwa produktu

Hydrogen chloride - 1-butanol solution, ~3 M in 1-butanol, derivatization grade (GC derivatization), LiChropur

grade

derivatization grade (GC derivatization)

Quality Level

form

solution

quality

LiChropur

reaction suitability

reagent type: derivatization reagent
reaction type: Acylations

concentration

~3 M in 1-butanol

technique(s)

gas chromatography (GC): suitable

density

0.87 g/mL at 20 °C

storage temp.

2-8°C

SMILES string

Cl

InChI

1S/ClH/h1H

InChI key

VEXZGXHMUGYJMC-UHFFFAOYSA-N

General description

Acylation, an alternative to silylation, is the conversion of compounds that contain active hydrogens (-OH, -SH and -NH) into esters, thioesters, and amides through the action of a carboxylic acid or derivative. The presence of a carbonyl group adjacent to the halogenated carbons enhances electron capture detector (ECD) response. Acylation has many benefits:
  • It improves the stability of compounds by protecting unstable groups.
  • It may confer volatility on substances such as carbohydrates or amino acids, which have so many polar groups that they are non-volatile and normally decompose on heating.
  • It assists in separations not possible with underivatized compounds.
  • Compounds are detectable at very low levels with an ECD.

Hydrogen chloride-1-butanol is a reagent utilized to form fragmentation-directing derivatives for GC/MS analysis.

Application

Hydrogen chloride - 1-butanol solution has been used for butylation of amino acids during blood sample analysis for determination of ethylenediaminetetraacetic acid using mass spectrometry.

Other Notes

Reagent for the esterification of amino acids and carnites for GC-MS analysis.

Legal Information

LiChropur is a trademark of Merck KGaA, Darmstadt, Germany
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Ta pozycja
909640760717934
grade

derivatization grade (GC derivatization)

grade

derivatization grade (GC derivatization)

grade

derivatization grade ((GC derivatization))

grade

derivatization grade (GC derivatization)

concentration

~3 M in 1-butanol

concentration

3 M in methanol

concentration

0.45-0.55 M in methanol, 0.5 M in methanol

concentration

~1.25 M HCl

Quality Level

100

Quality Level

100

Quality Level

100

Quality Level

100

form

solution

form

liquid

form

liquid

form

liquid

storage temp.

2-8°C

storage temp.

−20°C

storage temp.

2-8°C

storage temp.

2-8°C

density

0.87 g/mL at 20 °C

density

0.871-0.881 g/mL at 20 °C

density

0.801-0.812 g/mL at 20 °C

density

0.825 g/mL at 20 °C


signalword

Danger

Hazard Classifications

Acute Tox. 4 Oral - Eye Dam. 1 - Flam. Liq. 3 - Met. Corr. 1 - Skin Irrit. 2 - STOT SE 3

target_organs

Respiratory system

Klasa składowania

3 - Flammable liquids

wgk

WGK 1

ppe

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter



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Produkty

In this article we provide a complete workflow of quantification and identification of acylcarnitines in dried blood spots (DBS) using stable isotope-labeled (SIL) acylcarnitines CRMs by FIA-MS/MS.


M S Rashed et al.
Clinical chemistry, 43(7), 1129-1141 (1997-07-01)
Metabolic profiling of amino acids and acylcarnitines from blood spots by automated electrospray tandem mass spectrometry (ESI-MS/MS) is a powerful diagnostic tool for inborn errors of metabolism. New approaches to sample preparation and data interpretation have helped establish the methodology
Q Miao et al.
Physical review letters, 109(23), 233905-233905 (2013-02-02)
X-ray lasing is predicted to ensue when molecules are pumped into dissociative core-excited states by a free-electron-laser pulse. The lasing is due to the population inversion created in the neutral dissociation product, and the process features self-trapping of the x-ray
J Marwaha et al.
Experimental parasitology, 134(1), 12-17 (2013-02-16)
Intestinal cestodes with complex life cycles have to pass through the acid stomach lumen of their vertebrate host(s) in order to reach their preferred site of development. The cestode's tegument is the only organ in constant contact with this hostile



Numer pozycji handlu globalnego

SKUNUMER GTIN
87472-250ML-F04061833052730
87472-50ML-F04061833052747

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