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45520

Glufosinate-ammonium

PESTANAL®, analytical standard

Synonim(y):

2-Amino-4-(hydroxymethylphosphinyl)butyric acid ammonium salt, DL-Phosphinothricin

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Gabaryty przesyłkiSKUDostępnośćCena netto
100 mg
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424,00 zł

Informacje o tej pozycji

Wzór empiryczny (zapis Hilla):
C5H15N2O4P
Numer CAS:
Masa cząsteczkowa:
198.16
NACRES:
NA.24
PubChem Substance ID:
eCl@ss:
39110524
UNSPSC Code:
41116107
EC Number:
278-636-5
MDL number:
Beilstein/REAXYS Number:
8163399

424,00 zł


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grade

analytical standard

Quality Level

product line

PESTANAL®

shelf life

limited shelf life, expiry date on the label

technique(s)

HPLC: suitable, gas chromatography (GC): suitable

mp

215 °C

application(s)

agriculture
environmental

format

neat

SMILES string

N.CP(O)(=O)CCC(N)C(O)=O

InChI

1S/C5H12NO4P.H3N/c1-11(9,10)3-2-4(6)5(7)8;/h4H,2-3,6H2,1H3,(H,7,8)(H,9,10);1H3

InChI key

ZBMRKNMTMPPMMK-UHFFFAOYSA-N

General description

Glufosinate-ammonium is a phosphinic acid analog of glutamic acid.

Application

Glufosinate-ammonium may be used as a reference standard for the determination of the analyte in:
  • Human serum samples by mixed-mode solid-phase extraction (SPE), tert-butyldimethylsilyl (t-BDMS) derivatization and gas chromatography-mass spectrometry (GC-MS) operating on electron impact (EI) mode of detection.
  • Water samples by ion-exchange cleanup and derivatization followed by analysis using GC coupled to tandem mass spectrometry (MS/MS) equipped with EI mode of detection.
  • Finnish arable soils by high performance liquid chromatography combined with fluorescence detection (HPLC-FLD).[1]

Refer to the product′s Certificate of Analysis for more information on a suitable instrument technique. Contact Technical Service for further support.

Legal Information

PESTANAL is a registered trademark of Merck KGaA, Darmstadt, Germany
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Ta pozycja
49677PHR1689P8765
format

neat

format

neat

format

neat

format

-

technique(s)

HPLC: suitable, gas chromatography (GC): suitable

technique(s)

gas chromatography (GC): suitable

technique(s)

HPLC: suitable, gas chromatography (GC): suitable

technique(s)

-

grade

analytical standard

grade

certified reference material, TraceCERT®

grade

certified reference material, pharmaceutical secondary standard

grade

-

product line

PESTANAL®

product line

TraceCERT®

product line

-

product line

-

application(s)

agriculture
environmental

application(s)

agriculture
environmental

application(s)

pharmaceutical (small molecule)

application(s)

-

shelf life

limited shelf life, expiry date on the label

shelf life

limited shelf life, expiry date on the label

shelf life

-

shelf life

-


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pictograms

Health hazardExclamation mark

signalword

Danger

Hazard Classifications

Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Repr. 1B - STOT RE 2

Klasa składowania

6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

dust mask type N95 (US), Eyeshields, Faceshields, Gloves


Wykazy regulacyjne

Wykazy regulacyjne dotyczą głównie produktów chemicznych. Można w nich podawać ograniczoną liczbę informacji na temat produktów niechemicznych. Brak wpisu oznacza, że żaden ze składników nie znajduje się w wykazie. Użytkownik odpowiada za zagwarantowanie bezpiecznego i zgodnego z prawem stosowania produktu.

77182-82-2

CAS No.


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Protokoły

LC/MS Analysis of Glyphosate and Metabolites on apHera™ NH2, 2 mm I.D. Column

Produkty

Glifosat i związki pokrewne są mierzone w płatkach owsianych i płatkach dla niemowląt przy użyciu cząstek na bazie polimeru jonowymiennego do HPLC i SPE. Uzyskano niski poziom detekcji.

Glyphosate analysis: LC-MS/MS method with Supel™ Carbon LC U/HPLC column for stability and retention.

Glyphosate and related compounds are measured in oatmeal and infant cereal using ion-exchange polymer-based particles for HPLC and SPE. Low level detection was obtained.


Anna R Snapp et al.
Planta, 240(3), 599-610 (2014-07-16)
Co-expression of a lesquerella fatty acid elongase and the castor fatty acid hydroxylase in camelina results in higher hydroxy fatty acid containing seeds with normal oil content and viability. Producing hydroxy fatty acids (HFA) in oilseed crops has been a
Paola M Peltzer et al.
Ecotoxicology (London, England), 22(7), 1165-1173 (2013-07-23)
In this study, amphibian tadpoles of Hypsiboas pulchellus were exposed to herbicide Liberty®, which contains glufosinate ammonium (GLA), for 48 h to the following concentrations: 0 (control), 3.55, 4.74, 6.32, 8.43, 11.25, 15, 20, 26.6, and 35.5 mg GLA L(-1).
Griet Den Herder et al.
Plant physiology, 148(1), 369-382 (2008-07-05)
Protein ubiquitination is a posttranslational regulatory process essential for plant growth and interaction with the environment. E3 ligases, to which the seven in absentia (SINA) proteins belong, determine the specificity by selecting the target proteins for ubiquitination. SINA proteins are



Numer pozycji handlu globalnego

SKUNUMER GTIN
45520-100MG04061835377381

Questions

1–5 of 5 Questions  
  1. How can I determine the shelf life / expiration / retest date of this product?

    1 answer
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/418/501/product-dating-information-06-25-mk.pdf

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  2. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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  3. What is the Department of Transportation shipping information for this product?

    1 answer
    1. Transportation information can be found in Section 14 of the product's (M)SDS.To access the shipping information for this material, use the link on the product detail page for the product.

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  4. Product 45520, Glufosinate-ammonium, is a D, L isomer mix.  What proportions of each are in this product?

    1 answer
    1. This product is described as being racemic (DL).  Thus it would consist of 50% of the D- and 50% of the L- isomer.

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  5. How do I dissolve Product 45520, Glufosinate-ammonium?

    1 answer
    1. According to the chemicals encyclopedia published by the Royal Society of Chemistry, product 45520 is soluble in water.

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