15716

Boron trifluoride-methanol solution

~10% (~1.3 M), derivatization grade (GC derivatization), LiChropur^™

• Wzór liniowy: BF₃ · MeOH
• Numer CAS: 373-57-9
• Masa cząsteczkowa: 99.85
• UNSPSC Code: 12352104
• NACRES: NA.05
• PubChem Substance ID: 329750982
• EC Number: 206-766-4
• Beilstein/REAXYS Number: 3611499
• MDL number: MFCD00071635
• Concentration: ~10% (~1.3 M)
• Form: liquid
• Grade: derivatization grade (GC derivatization)

Właściwości

• grade: derivatization grade (GC derivatization)
• Quality Segment: 100
• product line: LiChropur^™
• form: liquid
• quality: LiChropur^™
• reaction suitability: reagent type: derivatization reagent; reaction type: Esterifications
• concentration: ~10% (~1.3 M)
• technique(s): gas chromatography (GC): suitable
• density: 0.86 g/mL at 20 °C
• storage temp.: 2-8°C
• SMILES string: CO.FB(F)F
• InChI: 1S/CH4O.BF3/c1-2;2-1(3)4/h2H,1H3;
• InChI key: JBXYCUKPDAAYAS-UHFFFAOYSA-N

Opis

General description

Boron trifluoride (BF3) is a Lewis acid; it is a very useful reagent for forming esters from acids. Boron trifluoride is commercially available as a 14% solution in methanol for forming esters derivatives. It catalysed reactions carried out in a water bath are very rapid and can be completed in a few minutes. Boron-trifluoride-catalysed transesterification of vegetable oils is one of the most popular methods. For transesterification of vegetable oils, BF3 is used in methanol (15 to 20% w/v).

Application

Learn more in the Product Information

Suitable for derivatization of hydroxy fatty acids.

Boron trifluoride-methanol solution may be used for catalysing a method, used for the synthesis of bishydroperoxides and their derivatives, based on a reaction of ketals with a solution of hydrogen peroxide in anhydrous ether. It may also be used for the rapid preparation of fatty acid esters for gas chromatographic analysis, as it converts fatty acids to their respective methyl esters in about 2 minutes.

Other Notes

Reagent for esterifying fatty acid for gas chromatographic analysis.

Reagent for methyl ester, O-acetyl.

Legal Information

LiChropur is a trademark of Merck KGaA, Darmstadt, Germany

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Informacja o środkach bezpieczeństwa

• pictograms: GHS02,GHS06,GHS08,GHS05
• signalword: Danger
• hcodes: H225,H301 + H311 + H331,H314,H370,H373
• pcodes: P210 - P233 - P280 - P303 + P361 + P353 - P304 + P340 + P310 - P305 + P351 + P338
• Hazard Classifications: Acute Tox. 3 Dermal - Acute Tox. 3 Inhalation - Acute Tox. 3 Oral - Eye Dam. 1 - Flam. Liq. 2 - Skin Corr. 1A - STOT RE 2 Inhalation - STOT SE 1
• target_organs: Eyes,Central nervous system, Kidney
• Klasa składowania: 3 - Flammable liquids
• wgk: WGK 3
• flash_point_f: 49.5 °F
• flash_point_c: 9.7 °C
• ppe: Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter