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1-Ethyl-3-methylimidazolium bis(trifluoromethylsulfonyl)imide

≥97.0% (NMR)

Synonim(y):

EMIM BTI, EMIM TFSI, EMIMIm

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Gabaryty przesyłkiSKUDostępnośćCena netto
1 g
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1140,00 zł
5 g
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3410,00 zł

Informacje o tej pozycji

Wzór empiryczny (zapis Hilla):
C8H11F6N3O4S2
Numer CAS:
Masa cząsteczkowa:
391.31
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352100
MDL number:
Assay:
≥97.0% (NMR)
Form:
liquid

1140,00 zł


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Quality Segment

assay

≥97.0% (NMR)

form

liquid

impurities

<0.5% water

functional group

fluoro

SMILES string

CCn1cc[n+](C)c1.FC(F)(F)S(=O)(=O)[N-]S(=O)(=O)C(F)(F)F

InChI

1S/C6H11N2.C2F6NO4S2/c1-3-8-5-4-7(2)6-8;3-1(4,5)14(10,11)9-15(12,13)2(6,7)8/h4-6H,3H2,1-2H3;/q+1;-1

InChI key

LRESCJAINPKJTO-UHFFFAOYSA-N

General description

1-Ethyl-3-methylimidazolium bis(trifluoromethylsulfonyl)imide [EMIM][N(Tf)2] is a room temperature ionic liquid (RTIL). ([EMIM][N(Tf)2]) as a non-aqueous solvent, is advantageous over traditional aprotic polar organic solvents in electrochemical investigation of electroactive species since it has low vapor pressure, high thermal stability, good conductivity and a wide electrochemical window. [EMIM][N(Tf)2] shows good solubility in CO2.

Application

[EMIM][N(Tf)2] may be used as a green solvent for the synthesis of zinc oxide (ZnO) nanoparticles under microwave conditions. It is useful in reactions which need a solvent with high CO2 solubility.

Physical form

fluorinated, hydrophobic ionic liquid

Other Notes

Enantioselective reactions in ionic liquids[1]

Legal Information

Product protected by U.S. Patent 5,827,602 assigned to Covalent Associates, Inc. Woburn, Ma, USA
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Danger

hcodes

Hazard Classifications

Acute Tox. 3 Oral

Klasa składowania

6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

ppe

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter



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Produkty

Ionic Liquids serve as non-aqueous electrolytes in electrochemical applications, valued for their conductivity and stability.

Ciecze jonowe służą jako niewodne elektrolity w zastosowaniach elektrochemicznych, cenione za ich przewodnictwo i stabilność.


Green synthesis of ZnO nanoparticles in a room-temperature ionic liquid 1-ethyl-3-methylimidazolium bis (trifluoromethylsulfonyl) imide.
Goharshadi EK, et al.
Journal of Physics and Chemistry of Solids, 69(8), 2057-2060 (2008)
Kinetic analysis of the reaction between electrogenerated superoxide and carbon dioxide in the room temperature ionic liquids 1-ethyl-3-methylimidazolium bis (trifluoromethylsulfonyl) imide and hexyltriethylammonium bis (trifluoromethylsulfonyl) imide
Buzzeo, Marisa C., et al.
The Journal of Physical Chemistry B, 108.12, 3947-3954 (2004)
Charging/discharging kinetics of poly (3, 4-ethylenedioxythiophene) in 1-ethyl-3-methylimidazolium bis-(trifluoromethylsulfonyl) imide ionic liquid under galvanostatic conditions
Randriamahazaka, H., et al.
Electrochimica Acta, 50.21, 4222-4229 (2005)



Numer pozycji handlu globalnego

SKUNUMER GTIN
GF84564490-1EA04061825383149
GF82866011-5EA04061821060976
GF82866011-2EA04061821060969
GF83157442-10EA04061829461935
GF85229545-50EA04061829593025
GF85285547-1EA04061825383552
GF85559989-10EA04061829469061
GF82706294-5EA04061821050540
GF00255664-10EA04061829473020
GF01519781-10EA04061821030795
GF01519781-2EA04061821030818
GF01858620-10EA04061829452599
GF01858620-20EA04061829544430
GF05509144-1EA04061825397191
267619-18G04061826134382
266353-500G04061826133866
266361-500G04061826133873
267619-4.5G04061826134399
267635-100G04061833596197
243469-100G04061838252647
243469-2KG04061825596341
209988-100G04061838770998
215503-1KG04061826714522
324930-50G04061826712368

Questions

1–3 of 3 Questions  
  1. How can I determine the shelf life / expiration / retest date of this product?

    1 answer
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/418/501/product-dating-information-06-25-mk.pdf

      Helpful?

  2. Would you be able to tell me the boiling point or thermal degradation temperature for this ionic liquid?

    1 answer
    1. The boiling range of this product is 543.6 °C / 1010.5 °F.

      Helpful?

  3. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

      Helpful?

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