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Merck

Bis(2-amino-thia-zole-4-acetato)aquazinc(II).

Acta crystallographica. Section E, Structure reports online (2009-01-01)
Lai-Jun Zhang, Xing-Can Shen, Yan Yang, Hong Liang
ABSTRACT

In the title compound, [Zn(C(5)H(5)N(2)O(2)S)(2)(H(2)O)], the central Zn atom (2 site symmetry) is five-coordinated by two N and three O atoms [Zn-N = 2.047 (3) Å, Zn-O = 2.099 (2) and 1.974 (4) Å] in a distorted square-pyramidal geometry. Besides one O atom from a water mol-ecule, two 2-amino-thia-zole-4-acetate ligands provide two N and two O atoms as coordinated atoms. In the crystal structure, inter-molecular O-H⋯O and N-H⋯O hydrogen bonds connect the mol-ecules into an infinite three-dimensional framework.

MATERIALS
Product Number
Brand
Product Description

Sigma-Aldrich
Ethyl 2-aminothiazole-4-acetate, 99%