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Merck

Direct carbamoylation of alkenyl halides.

Organic letters (2003-12-20)
Robert F Cunico, Bikash C Maity
PMID14682736
ABSTRACT

Alkenyl chlorides and bromides are converted into tertiary enamides by treatment with a carbamoylsilane in toluene at 110 degrees C in the presence of phosphine-palladium(0) catalysts. [reaction: see text]