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  • Poly(anhydride-ester) and poly(N-vinyl-2-pyrrolidone) blends: salicylic acid-releasing blends with hydrogel-like properties that reduce inflammation.

Poly(anhydride-ester) and poly(N-vinyl-2-pyrrolidone) blends: salicylic acid-releasing blends with hydrogel-like properties that reduce inflammation.

Macromolecular bioscience (2014-10-22)
Michelle A Ouimet, Renata Fogaça, Sabrina S Snyder, Sameer Sathaye, Luiz H Catalani, Darrin J Pochan, Kathryn E Uhrich
ABSTRACT

Polymers such as poly(N-vinyl-2-pyrrolidone) (PVP) have been used to prepare hydrogels for wound dressing applications but are not inherently bioactive. For enhanced healing, PVP was blended with salicylic acid-based poly(anhydride-esters) (SAPAE) and shown to exhibit hydrogel properties upon swelling. In vitro release studies demonstrated that the chemically incorporated drug (SA) was released from the polymer blends over 3-4 d in contrast to 3 h, and that blends of higher PVP content displayed greater swelling values and faster SA release. The polymer blends significantly the inflammatory cytokine, TNF-α, in vitro without negative effects.

MATERIALS
Product Number
Brand
Product Description

Supelco
Salicylic acid, Pharmaceutical Secondary Standard; Certified Reference Material
Sigma-Aldrich
Salicylic acid, ACS reagent, ≥99.0%
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Chloroform, anhydrous, ≥99%, contains 0.5-1.0% ethanol as stabilizer
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Salicylic acid, ≥99%, FG
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Tetrahydrofuran, anhydrous, ≥99.9%, inhibitor-free
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Triethylamine, BioUltra, ≥99.5% (GC)
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Triethylamine, ≥99.5%
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Triethylamine, puriss. p.a., ≥99.5% (GC)
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Salicylic acid, ReagentPlus®, ≥99%
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Triethylamine, ≥99%
USP
Salicylic acid, United States Pharmacopeia (USP) Reference Standard
Supelco
Chloroform, Pharmaceutical Secondary Standard; Certified Reference Material
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Triethylamine, ≥99.5%
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Chloroform, contains 100-200 ppm amylenes as stabilizer, ≥99.5%
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Chloroform, biotech. grade, ≥99.8%, contains 0.5-1.0% ethanol as stabilizer
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Chloroform, ACS spectrophotometric grade, ≥99.8%, contains 0.5-1.0% ethanol as stabilizer
Supelco
Tetrahydrofuran, Pharmaceutical Secondary Standard; Certified Reference Material
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Chloroform, HPLC Plus, for HPLC, GC, and residue analysis, ≥99.9%, contains 0.5-1.0% ethanol as stabilizer
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Chloroform, suitable for HPLC, ≥99.8%, amylene stabilized
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Chloroform, suitable for HPLC, ≥99.8%, contains 0.5-1.0% ethanol as stabilizer
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Chloroform, HPLC Plus, for HPLC, GC, and residue analysis, ≥99.9%, contains amylenes as stabilizer
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Tetrahydrofuran, inhibitor-free, suitable for HPLC, ≥99.9%
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Pyridine, ≥99%
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Dichloromethane, suitable for HPLC, ≥99.9%, contains 40-150 ppm amylene as stabilizer
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Pyridine, anhydrous, 99.8%
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