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Fate of phosphorus in diluted urine with tap water.

Chemosphere (2014-07-30)
Xiaoning Liu, Guoqi Wen, Huihui Wang, Xiaoqi Zhu, Zhengyi Hu
ABSTRACT

P loss during the fresh urine storage process is inevitable because of the presence of Ca and Mg. Dilution is one of the most important parameters influencing urine composition and subsequent P recovery. This study aimed to investigate the fate of P in urine with different dilution ratios (Vwater/Vurine, i.e., 0/100, 25/75, 50/50 and 75/25). The results indicate that the percentage of P loss increased from 43% to 76% as the dilution ratio increased from 0/100 to 75/25 because of more Ca and Mg obtained from tap water. Meanwhile, P removal efficiency through struvite precipitation decreased from 51% to 8% because of lower supersaturation ratio as a result of dilution. Struvite crystals with high purity were still obtained even under a dilution ratio of 50/50 urine solution. Batch experiments were also performed to study the influence of temperature (15-35°C) on P recovery and crystal size. For different dilution ratios of urine solutions, no significant discrepancy for the P removal efficiencies were observed at 15 and 35°C, whereas the P removal efficiencies at 25°C showed an increasing gap with those at 15 and 35°C. The largest average crystal sizes were found at 25°C, which was opposite to the trend of P removal efficiency.

MATERIALS
Product Number
Brand
Product Description

Sigma-Aldrich
Water, Nuclease-Free Water, for Molecular Biology
Sigma-Aldrich
Magnesium, ribbon, ≥99.0% Mg basis
Supelco
Water, suitable for ion chromatography
Supelco
Water, ACS reagent, for ultratrace analysis
Sigma-Aldrich
Water, suitable for HPLC
Sigma-Aldrich
Water, HPLC Plus
Sigma-Aldrich
Phosphorus, red, ≥99.99% trace metals basis