- Ionic liquid-immobilized quinuclidine-catalyzed Morita-Baylis-Hillman reactions.
Ionic liquid-immobilized quinuclidine-catalyzed Morita-Baylis-Hillman reactions.
The Journal of organic chemistry (2005-03-12)
Xueling Mi, Sanzhong Luo, Jin-Pei Cheng
PMID15760226
ABSTRACT
[reaction: see text] The ionic liquid-bound quinuclidine catalyzed Baylis-Hillman reactions were investigated. The IL-supported catalyst showed equally good catalytic activity as compared with its nonimmobilized counterpart. The corresponding Baylis-Hillman adducts were obtained in moderate to high yields in all the cases tested. The IL-supported quinuclidine can be readily recovered and reused six times without significant loss of catalytic activity.