259039

Chloro(1,5-hexadiene)rhodium(I),dimer

98%

• Synonym(s): Di-μ-chlorobis[(1,2,5,6-η)-1,5-hexadiene]dirhodium
• Linear Formula: [(H₂C=CHCH₂CH₂CH=CH₂)RhCl]₂
• CAS Number: 32965-49-4
• Molecular Weight: 434.96
• MDL number: MFCD00064595
• UNSPSC Code: 12161600
• PubChem Substance ID: 24855679
• NACRES: NA.22

Properties

• Assay: 98%
• reaction suitability: core: rhodium; reagent type: catalyst
• mp: 118-120 °C (lit.)
• SMILES string: Cl[Rh].Cl[Rh].C=CCCC=C.C=CCCC=C
• InChI: 1S/2C6H10.2ClH.2Rh/c2*1-3-5-6-4-2;;;;/h2*3-4H,1-2,5-6H2;2*1H;;/q;;;;2*+1/p-2
• InChI key: HXNWPVBAYNUADR-UHFFFAOYSA-L

Description

Application

Catalyst for:

• Hydrogenation
• Enantioselective hydrosilylation

Useful catalyst for the reduction of arenes and heterocyclic compounds using CTAB or THS as phase-transfer catalyst.

Safety Information

• Pictograms: GHS05,GHS07
• Signal Word: Danger
• Hazard Statements: H315,H318,H335
• Precautionary Statements: P261 - P264 - P271 - P280 - P302 + P352 - P305 + P351 + P338
• Hazard Classifications: Eye Dam. 1 - Skin Irrit. 2 - STOT SE 3
• Target Organs: Respiratory system
• Storage Class Code: 11 - Combustible Solids
• WGK: WGK 3
• Flash Point(F): Not applicable
• Flash Point(C): Not applicable