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Sigma-Aldrich

(N-Boc-2-pyrrolyl)dimethylsilanol

97%

Synonym(s):

N-Boc-2-(hydroxydimethylsilyl)pyrrole

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About This Item

Linear Formula:
((CH3)3COC(O))(C4H3N)(Si(CH3)2(OH))
CAS Number:
879904-82-2
Molecular Weight:
241.36
MDL number:
MFCD08457657
UNSPSC Code:
12352103
PubChem Substance ID:
24885023
NACRES:
NA.22

Assay

97%

form

solid

mp

48-57 °C

storage temp.

2-8°C

SMILES string

CC(C)(C)OC(=O)n1cccc1[Si](C)(C)O

InChI

1S/C11H19NO3Si/c1-11(2,3)15-10(13)12-8-6-7-9(12)16(4,5)14/h6-8,14H,1-5H3

InChI key

RLDVDBYGGISJNL-UHFFFAOYSA-N

Application

(N-Boc-2-pyrrolyl)dimethylsilanol can be used as a substrate:
  • To prepare cross-coupling products by reacting with various aryl iodides.
  • In the synthesis of alkoxyhydrosiloxanes by reacting with alkoxyhydrosilanes.

Pictograms

Exclamation mark
GHS07

Signal Word

Warning

Hazard Statements

H315,H319,H335

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

Target Organs

Respiratory system

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

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Organosilicon Chemistry
Denmark SE and Baird JD
Aldrich Chemfiles, 6(5), 1-14 (2006)
Palladium-catalyzed cross-coupling reactions of heterocyclic silanolates with substituted aryl iodides and bromides
Denmark SE and Baird JD
Organic Letters, 8(4), 793-795 (2006)
A catalyst-and additive-free synthesis of alkoxyhydrosiloxanes from silanols and alkoxyhydrosilanes
Satoh Y, et al.
Chemical Communications (Cambridge, England), 56(59), 8218-8221 (2020)
Denmark, S. E.; Ober, M. H.
Aldrichimica Acta, 36, 75-75 (2003)

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