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224391

Sigma-Aldrich

Propylmagnesium chloride solution

2.0 M in diethyl ether

Synonym(s):

n-Propylmagnesium chloride, Chloropropylmagnesium

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About This Item

Linear Formula:
CH3CH2CH2MgCl
CAS Number:
Molecular Weight:
102.85
Beilstein:
3600246
MDL number:
UNSPSC Code:
12352103
PubChem Substance ID:
NACRES:
NA.22

reaction suitability

reaction type: Grignard Reaction

concentration

2.0 M in diethyl ether

density

0.827 g/mL at 25 °C

SMILES string

CCC[Mg]Cl

InChI

1S/C3H7.ClH.Mg/c1-3-2;;/h1,3H2,2H3;1H;/q;;+1/p-1

InChI key

AMXVKMXLDJXAPM-UHFFFAOYSA-M

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Application

Propylmagnesium chloride solution can be used as a Grignard reagent:
  • For the determination of analytes via derivatization reaction.
  • To synthesize alkyl naphthyl ketones from naphthonitriles.

Signal Word

Danger

Hazard Statements

Hazard Classifications

Acute Tox. 4 Oral - Eye Dam. 1 - Flam. Liq. 2 - Skin Corr. 1B - STOT SE 3 - Water-react 2

Target Organs

Central nervous system

Supplementary Hazards

Storage Class Code

4.3 - Hazardous materials which set free flammable gases upon contact with water

WGK

WGK 1

Flash Point(F)

-40.0 °F - closed cup

Flash Point(C)

-40 °C - closed cup

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

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Synthesis of n-Alkylnaphthalenes via Semicarbazones
ZENGIN G, et al.
Turkish Journal of Chemistry, 30, 139-144 (2006)

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