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  • Effect of lithium chloride on spectral, optical, thermal and mechanical behaviour of bis thiourea zinc acetate crystals.

Effect of lithium chloride on spectral, optical, thermal and mechanical behaviour of bis thiourea zinc acetate crystals.

Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy (2012-08-08)
L Ruby Nirmala, J Thomas Joseph Prakash
ABSTRACT

Single crystals of pure bis thiourea zinc acetate (BTZA) and lithium chloride (LiCl) doped BTZA have been synthesized and grown successfully from aqueous solutions by slow evaporation technique. The single crystals thus grown were characterized by different techniques such as single crystal XRD, AAS, FT-IR, UV-Vis, TG/DTA and SHG test. The single crystal XRD study proved that the dopant has not changed the structure of the parent crystal. The AAS study confirmed the presence of lithium in the doped crystal. The FTIR study ascertained the metal coordination of lithium chloride doped BTZA through thiourea. The optical behavior of the doped crystal has been examined by UV spectral analysis. Thermal studies TGA & DTA of the doped crystal have been investigated and found that the doped crystal is thermally more stable than the pure crystal. The SHG test using Nd: YAG Laser confirmed the NLO activity of the pure and doped crystal. The obtained results are presented and discussed.

MATERIALS
Product Number
Brand
Product Description

Sigma-Aldrich
Zinc acetate dihydrate, 99.999% trace metals basis
Sigma-Aldrich
Zinc acetate dihydrate, reagent grade
Sigma-Aldrich
Zinc acetate dihydrate, puriss. p.a., ACS reagent, ≥99.0% (KT)
Sigma-Aldrich
Zinc acetate dihydrate, ACS reagent, ≥98%