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  • Novel chemosensor for the visual detection of copper(II) in aqueous solution at the ppm level.

Novel chemosensor for the visual detection of copper(II) in aqueous solution at the ppm level.

Inorganic chemistry (2012-08-08)
Vadapalli Chandrasekhar, Sourav Das, Rajeev Yadav, Sakiat Hossain, Rashmi Parihar, Ganesh Subramaniam, Pratik Sen
ABSTRACT

A new water-soluble, multisite-coordinating ligand LH(7) was prepared by the condensation of tris(hydroxymethyl)aminomethane with 2,6-diformyl-p-cresol. LH(7) is a selective chemosensor for Cu(2+), under physiological conditions, with visual detection limits of 20 ppm (ambient light conditions) and 4 ppm (UV light conditions). LH(7) can also be used in biological cell lines for the detection of Cu(2+).

MATERIALS
Product Number
Brand
Product Description

Sigma-Aldrich
Trizma® base, puriss. p.a., ≥99.7% (T)
Supelco
Trizma® base, reference material for titrimetry, certified by BAM, >99.5%
Sigma-Aldrich
Trizma® base, ≥99.0% (T)
Sigma-Aldrich
Trizma® base, BioUltra, for molecular biology, ≥99.8% (T)
Sigma-Aldrich
Tris(hydroxymethyl)aminomethane, ACS reagent, ≥99.8%
Sigma-Aldrich
Trizma® base, BioXtra, pH 10.5-12.0 (1 M in H2O), ≥99.9% (titration)
Sigma-Aldrich
Trizma® base, BioPerformance Certified, meets EP, USP testing specifications, suitable for cell culture, ≥99.9% (titration)
Sigma-Aldrich
Trizma® base, Primary Standard and Buffer, ≥99.9% (titration), crystalline
Sigma-Aldrich
Trizma® base, ≥99.9% (titration), crystalline
Sigma-Aldrich
Tromethamine, meets USP testing specifications
Sigma-Aldrich
Sigma 7-9®, ≥99% (titration), crystalline
SAFC
Tromethamine