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  • Study and modeling of the evolution of gas-liquid partitioning of hydrogen sulfide in model solutions simulating winemaking fermentations.

Study and modeling of the evolution of gas-liquid partitioning of hydrogen sulfide in model solutions simulating winemaking fermentations.

Journal of agricultural and food chemistry (2015-03-13)
Jean-Roch Mouret, Jean-Marie Sablayrolles, Vincent Farines
RESUMEN

The knowledge of gas-liquid partitioning of aroma compounds during winemaking fermentation could allow optimization of fermentation management, maximizing concentrations of positive markers of aroma and minimizing formation of molecules, such as hydrogen sulfide (H2S), responsible for defects. In this study, the effect of the main fermentation parameters on the gas-liquid partition coefficients (Ki) of H2S was assessed. The Ki for this highly volatile sulfur compound was measured in water by an original semistatic method developed in this work for the determination of gas-liquid partitioning. This novel method was validated and then used to determine the Ki of H2S in synthetic media simulating must, fermenting musts at various steps of the fermentation process, and wine. Ki values were found to be mainly dependent on the temperature but also varied with the composition of the medium, especially with the glucose concentration. Finally, a model was developed to quantify the gas-liquid partitioning of H2S in synthetic media simulating must to wine. This model allowed a very accurate prediction of the partition coefficient of H2S: the difference between observed and predicted values never exceeded 4%.

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Sigma-Aldrich
Hydrogen sulfide, ≥99.5%
Sigma-Aldrich
Hydrogen sulfide solution, 0.8 M in THF
Sigma-Aldrich
Sulfur-32S, 99.9 atom % 32S
Sulfur-32S solution, IRMM®, certified reference material, Spike Isotopic Reference Material
Sulfur-32S solution, IRMM®, certified reference material, Spike Isotopic Reference Material
Sulfur-32S solution, IRMM®, certified reference material, Spike Isotopic Reference Material