Covalent modification of a metal-organic framework with isocyanates: probing substrate scope and reactivity.

Covalent modification of a metal-organic framework with isocyanates: probing substrate scope and reactivity.

Chemical communications (Cambridge, England) (2008-07-18)

Emily Dugan, Zhenqiang Wang, Marilyn Okamura, Annette Medina, Seth M Cohen

RESUMEN

Isoreticular metal-organic framework-3 (IRMOF-3) has been postsynthetically modified with isocyanates to generate unprecedented, microporous urea-functionalized frameworks.

MATERIALES

Referencia del producto

Marca

Descripción del producto

144452

Sigma-Aldrich

tert-Butyl isocyanate, 97%

252646

Sigma-Aldrich

(Trimethylsilyl)isocyanate, 85%